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Can INS measurements access hydrocarbonaceous overlayers on heterogeneous hyd...
This application seeks to discover whether the catalyst handling protocols refined for INS measurements of a variety of heterogeneous catalytic systems can be further exploited... -
The interaction of hydrogen with gallium oxide
There is an increasing interest in the application of gallium oxide as a catalyst support material, with particular interest in its use in new methanol steam reforming... -
Determination of the structure of methoxy on eta-alumina
We have recently demonstrated that we are able to obtain structural information about adsorbed hydrogenous species from a variety of metal catalysts. We emphasise that this is a... -
Towards an improved understanding of the active phase of iron based Fischer-T...
The applicants have recently completed a series of INS studies on a model iron Fischer-Tropsch catalyst. That work established that different sample pre-treatments could... -
INS Study of Cu-based methanol synthesis catalysts
In low-pressure methanol synthesis from fossil synthesis gas, Cu/ZnO/Al2O3-catalysts are successfully used in industrial synthesis at 250°C and 50-100 bar, but the exact... -
The use of INS to characterise prototype methane reforming catalysts over a r...
Previous work by the experimental team has successfully examined methane reforming catalysts using CO2 as the oxidant. Unfortunately, the progression to using steam as the... -
High resolution INS spectra of hydrocarbonaceous overlayers formed on novel m...
For the first time, the research team aim to use INS to characterise a series of new high specification methane reforming catalysts. The enhanced performance of these catalysts... -
Can a magnetic transition recently discovered on iron-based Fischer-Tropsch c...
The applicants have used a recent EPSRC award to develop protocols by which INS can be used to investigate methane reforming catalysts. That work is now complete and we have... -
The adsorption of methyl proprionate on silica catalysts.
Commercial routes for the manufacture of methyl methacrylate monomer have recently been developed that involve the reaction of esters over modified silicas, which are amphoteric... -
The application of INS to investigate the active phase of methane steam refor...
A previous allocation of beamtime on MAPS [RB720354] revealed the vibrational fingerprint of methane reforming catalysts operating under so-called ¿dry¿ reforming conditions.... -
Characterisation of intermediates in CO oxidation over Pd/Al2O3.
Recent infrared measurements by one of the applicants (GR) have shown that CO and CO2 adsorption on alumina-supported palladium catalysts form a variety of carbonate species. In... -
How do modifiers affect performance in iron Fischer-Tropsch catalysts?
The applicants have recently completed a series of INS studies on a model iron Fischer-Tropsch catalyst. Given the recent huge invigoration of F-T catalysis due to future global... -
Can INS measurements access hydrocarbonaceous overlayers on heterogeneous hyd...
This application seeks to discover whether the catalyst handling protocols refined for INS measurements of a variety of heterogeneous catalytic systems can be further exploited... -
The use of INS to investigate reactions relevant to Fischer-Tropsch catalysis
In collaboration with an industrial partner, the PI is seeking to use INS to help characterise a series of catalysts active for the important Fischer-Tropsch (F-T) process. As... -
The adsorption of methyl proprionate on silica catalysts.
Commercial routes for the manufacture of methyl methacrylate monomer have recently been developed that involve the reaction of esters over modified silicas, which are amphoteric... -
Characterisation of tunnelling modes of adsorbed methoxy on eta-alumina
Our previous proposal strongly suggested that the methyl groups of adsorbed methoxy on eta-alumina do exhibit tunnelling. This application aims to provide additional evidence to... -
Does the methyl group of adsorbed methoxy on eta-alumina tunnel?
This application seeks to discover whether it is possible to observe the tunnelling of the methyl groups of adsorbed methoxy on eta-alumina. To our knowledge, this is the first... -
The application of INS to examine high specification Fe Fischer-Tropsch catal...
Over the last 4-5 years the research team have been developing INS methodology that can be applied to investigate Fe Fischer-Tropsch (F-T) catalysts. The first stage of that... -
Changes to the structure of natural lung surfactant, and extracted proteins, ...
The presence of a monolayer of surfactant material at the air-water interface of the lung is crucial for respiratory function. It is well known that exposure to the ubiquitous... -
Quantification of hydrocarbonaceous overlayers relevant to the induction of i...
Recent experiences applying INS to examine a series of nickel-based methane reforming catalysts have enabled a generic experimental methodology to be developed. In collaboration...