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The structure of hydrogen in calcium-ammonia-graphite: an in situ time resolv...
The aim of this proposal is to determine the in-plane and out-of-plane structure of H2 in the two dimensional galleries of stage-I calcium-ammonia-graphite intercalates: this... -
High-pressure studies of energetic materials
This proposal seeks to identify and characterise high-pressure polymorphs of the energetic materials hydroxylammonium perchlorate, CL-20, diaminodinitroethene (FOX-7), and... -
Bi-disperse colloids: silica and microemulsions
Surprisingly little work has been done to gain understanding about the nature, stability and properties of nanoparticles dispersed in organic solvents (organosols). Recently... -
Oxygen Vacancy Clusters in Pure and Doped CeO2-d
Oxide ceramics based on ceria, CeO2, have been the subject of considerable research for the role of solid electrolyte within solid oxide fuel cells (SOFCs), since their ionic... -
Simultaneous INS and Raman studies of lysozyme
The proposers have obtained a dispersive Raman spectrometer that is fibre optically coupled to a custom centrestick that will allow simultaneous Raman and neutron measurements.... -
Vibrational Dynamics of Alkali Silicate Glasses - An Isotopic Mass Contrast S...
The present proposal is part of a larger EPSRC project advancing the vibrational spectroscopy of silicate glasses. The project involves the techniques of IR and Raman... -
Understanding drug carrier interactions in the stomach
In a pharmaceutical industry context, hydrophilic polymeric matrices are a popular methodology for extending the release of drugs. However, issues sometimes arise -... -
High-pressure and variable-temperature studies of RDX
Previous studies have suggested that a high-pressure form of the widely used secondary explosive RDX can be obtained above ~4 GPa and 488 K. This phase is reported to be... -
Studies of the mechanism of hydrotropy
The objective is to refine current understanding about the mechanism of hydrotropy with respect to polarity and electrostatic character of hydrotropes and hydrophobic solutes... -
High-pressure studies of energetic materials
This proposal seeks to identify and characterise high-pressure polymorphs of the energetic materials hydroxylammonium perchlorate, CL-20, diaminodinitroethene (FOX-7), and... -
Gold-loaded microgels
Recent results show that gold nanoparticles (Au-NPs) can be included into microgels (MGs). UV-visible spectra (Figure 1) suggest the original Au-NP sols retain their size and... -
Opening up microemulsion phases in CO2
New types of water-in-CO2 microemulsions using mixed surfactant systems will be investigated by high-pressure SANS (HP-SANS). Exciting new results (see report on RB820030) have... -
Self-assembly in biosurfactants and biosurfactant / surfactant mixtures
This proposal is part of a new project which is a collaboration between Oxford, Newcastle, Ulster, and Unilever on the development of sustainable laundry detergents, using... -
Polyamorphism in Glassy GeO2
The object of this proposal is to determine, by using neutron diffraction, the nature of the polyamorphic phase transition that occurs in glassy GeO2 with increasing pressure.... -
Surface Active Carbene (Surfenes) Precursors and Complexes
Within the last decade N-heterocyclic carbene (NHC) ligands have been widely recognised for their numerous catalytic applications. However, despite their widespread use as... -
Emission Enhancing Micelles and Microemulsions for the Analytical Sciences
Nuclear power has played an important role in Britain¿s history and is set to play an equally important role in its future. We have recently established a network involving... -
Close control over microemulsion stability using blended solvents
The aim of this proposal is to investigate a novel approach to phase separation in microemulsions using careful choice of organic solvents, and appropriate mixtures.... -
Organogels for applications in CO2
This proposal aims to explore organogel systems, like those recently decsribed1-3, but made from new CO2 philic surfactant-gelators. These have been synthesised to feature... -
Evolving microemulsions - tuning selectivity in oxidation reactions
We have begun to explore the synthesis, reactivity and physicochemical properties of a number of surface-active metal complexes, to devise a method for the catalytic... -
Characterising micelles formed from new polymerizable amphiphiles derived fro...
Amphiphiles derived from amino acids are important functional materials. The amino, carboxyl and side chain groups present in the chemical structure of amino acids provide wide...