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Organometallic Radicals
A 19-electron organometallic radical was produced by the reaction of muonium with ferrocene and characterized by avoided level crossing muon spin resonance (ALC-muSR) and... -
Spin relaxation of short-lived spin-labelled radicals in solution
The spin relaxation rates of free radicals in solution can provide valuable information about the dynamics of molecular tumbling in solution, and solvent-radical interactions.... -
Kinetics of Hydrogen Abstraction in Alkanes by Mu Reactivity studied by RF Re...
Hydrogen abstraction reactions are key steps in free radical mechanisms that dominate the combustion and atmospheric chemistry of the alkane hydrocarbons and, as such, merit... -
Novel Mechanisms of Green Tea Anti-Oxidants by Mu-SR, INS and DFT Experiments
A proposal is made to continue ongoing ALC-muSR experiments on the green-tea anti-oxidant EGCG and its analogue. Several overlapping resonances observed on HiFi made it... -
High Field Studies of BEDT-TTF and kappa-(BEDT-TTF)2X
The kappa structural phase of BEDT-TTF salts incorporating various anions X provides an extremely interesting series of layered-structure strongly-correlated materials, whose... -
Identification and dynamics of muon states in octabutoxy-phthalocyanine
The current experiment proposes to identify and study the spin dynamics of the muon states formed in octabutoxy-phthalocyanine (oBu-H2Pc) using the avoided level crossing... -
RF μSR in the gas phase: understanding a ¿null¿ result
We have made a significant effort to develop Radio Frequency μSR (RF μSR) as a technique for spectroscopy of organic radicals in the gas phase. Realising this method... -
muSR in the presence of significant spin-orbit coupling
The great majority of known muonium defect centres and muonium substituted organic radicals have essentially spin-only magnetism, with few exhibiting any noticeable departure... -
Molecular Dynamics in Polystyrene
A basic understanding of the dynamic processes in polystyrene (PS) is a question of utmost interest and has technological ramifications due to its importance in commercial... -
RF μSR in the gas phase: understanding a null result (continued)
We have made a significant effort to develop Radio Frequency μSR as a technique for spectroscopy of organic radicals in the gas phase. This would be a particularly... -
Muon spin-relaxation probe of chiral spin-liquid state in YBaCo4O7
Geometrically frustrated antiferromagnets RBa(Co/Fe)4O7 (R=rare earth or Y) exhibit a weak ferromagnetic component in the high-temperature spin-liquid phase. Based on a symmetry... -
Quantum State Manipulation in PTFE.
Discrete energy level form in quantum mechanical systems and if carefully measured the population density of the levels can be probed and manipulated. The consequence of this... -
Repolarization of Radicals in Liquids (RB920344)
The recovery of the muon polarization in a longitudinal magnetic field has been used to obtain the muon hfcs of organic radicals. In pure benzene there is a single step in the... -
The effect of metal nanoparticles on the electronic structure of bound free r...
In recent years, the noble metals nanoparticles (MNPs) have been the subject of intense interest in areas of materials science, biotechnology, medicine and organic chemistry for... -
End-Game: Cornering Solvent Effects on H-Addition in Green Tea Anti-Oxidants
Our ongoing project to characterise radical scavenging by the green tea anti-oxidant EGCG and its D-ring analogue, (3,4,5-(OH)3-Bz) is near-complete. ALC-MuSR experiments on the... -
Characterisation of Green-Tea Radical Scavengers by ALC-MuSR and High-Level C...
We propose to characterise selected radical structures of the green-tea anti-oxidant flavenoid EGCG (& selected analogues), by DFT/post-HF computation and ALC-MuSR, towards... -
Kinetics of Hydrogen Abstraction in Alkanes by Mu Reactivity studied by RF Re...
Hydrogen abstraction reactions are key steps in free radical mechanisms that dominate the combustion and atmospheric chemistry of the alkane hydrocarbons and, as such, merit... -
Kinetics of Hydrogen Abstraction in Alkanes by Mu Reactivity studied by RF Re...
Hydrogen abstraction reactions are key steps in free radical mechanisms that dominate the combustion and atmospheric chemistry of the alkane hydrocarbons and, as such, merit... -
Commissioning Proposal ¿ Gas Cell Development
An important element of the work associated with the current Framework Programme 7 Joint Research Activity (JRA) for muons is the development of gas sample pressure cells... -
Population Control of Entangled Levels PTFE
We have recently performed a test experiment which demonstrates the potential (RB1510281) of using RF muon spectroscopy to manipulate the population of the levels of the FmuF...