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In situ investigation of templated polymerisation
Metal organic frameworks (MOFs) are a particularly interesting class of three dimensional crystalline networks formed by the self-assembly of metal ions with organic ligands.... -
Quad-chain surfactants for CO2
In recent years much progress has been made in the design of surfactants that are soluble in liquid CO2; hence these additives able to modify physicochemical properties... -
Surfactant aggregation in magnetic ionic liquids
This proposal aims to explore aggregation behavior of common surfactants in magnetic ionic liquids (MILs) and to investigate the effect of a magnetic field on aggregate size,... -
Tuning morphology of nonionic highly-methylated surfactant/water/CO2 assemblies
This proposal aims to explore a cheaper and more environmental-benign surfactants for microemulsion formation in CO2; in other words, a low fluorine containing... -
Tuning micellar interfacial curvature in CO2 by small molecule additives
This proposal aims to explore co-surfactants, as additives with CO2-active surfactants, for elongating reversed micelles in dense CO2 by using high-pressure small-angle neutron... -
Polyelectrolyte surfactant complexes
Approved proposal under the ICRD Scheme Proposal ICRD0005 -
Resolving mixing.demixing effects in hydrocarbon/fluorocarbon micelles
Surfactants ability to lower surface tension and act as solubilising agents is critical for their wide use in everyday products. An oily hydrocarbon (HC) "tail group" attached... -
Are hydrotropes a unique class of solutes?
The aim is to improve understanding of solution properties and aggregation of hydrotropes and alkyl¿hydrotropes, and the relationship with common surfactants. Although they are... -
Low surface energy materials (LSEMs) from new hydrocarbon architectures
The research topic is Low surface energy materials (LSEMs), and development of new hydrocarbon architectures as replacements for environmentally hazardous fluorocarbon... -
Manipulation of the aggregate curvature in water/dense CO2 system
This proposal aims to investigate how the curvature of surfactant assemblies in water/dense CO2 systems can be tuned via the design and mixing of CO2-phillic surfactants. One... -
Optimising chemical structure of CO2-philic hybrid surfactants for stabilisin...
The proposal aims to explore water-in-CO2 (w/c) microemulsions with very promising hybridCO2-philic surfactants. The surfactants have been systematically synthesised... -
Co-micellization of hydrotropes and surfactants
This proposal builds on recent work with hydrotropes alone (Langmuir, 2011, 27, 12346-12353); now co-micellisation of hydrotropes with surfactants will be investigated. The aim... -
Measuring the bending rigidity of surfactant films in water-in-CO2 microemu...
This proposal aims to expand knowledge about water-in-CO2(w/c) microemulsions by studying the ¿bending rigidity¿ of surfactant films, which has been frequently tested on normal... -
The viscosity control of supercritical CO2 using microemulsions and hydrotrop...
One of the most commonly used supercritical fluids is carbon dioxide (scCO2) which is non-toxic, non-flammable, abundant and has an easily accessible critical point. An... -
Microemulsions stabilized by magnetic surfactants
Surfactant systems responsive to pH, temperature, CO2, and light are known. Our new work has shown for the first time, magneto-responsive surfactants (also being ionic liquids... -
Optimal fluorination and structure of triple-fluorocarbon-tail surfactants fo...
This proposal aims to explore optimal fluorine (F) content and chain architecture in triple-fluorocarbon (FC)-tail surfactants used as CO2-philic solubilizers for water-in-CO2... -
Contrast variation SANS to understand drug directed assembly of multi lamella...
Recurring infection following dental interventions such as fillings is the most common reason for failure, leading to further treatments including root canal therapy, where the... -
Surfactant mixtures in CO2
Studies by the Bristol group, and elsewhere [1, 2], have shown that highly branched hydrocarbon chains is the key factor for generating effective non-fluorous CO2 philic... -
A new approach to viscosity enhancement of oils and CO2
Due to the naturally low viscosity of liquid CO2 (0.1-1.0 cP pressure/temperature dependent) the CO2 is prone to ¿fingering¿, limiting the efficiency of CO2-EOR [1]. In order to... -
Mechanism of charging metal oxide colloids in non-polar solvents
Contrast-variation SANS (CV SANS) will be used to determine how surfactant inverse micelles interact with model metal oxide colloids. By using deuterated surfactant (D-AOT) with...