The high temperature phases of multiferroic YMnO3

DOI

Hexagonal YMnO3 is a well-studied, but poorly understood, multiferroic material, which adopts the 'geometric' mechanism of ferroelectric distortion, rather than the more normal mechanisms mediated via the second-order Jahn-Teller effect (the 'd0' or 'lone-pair' mechanisms). Despite several recent high temperature powder diffraction studies, by both X-ray and neutron methods, the nature of the evolution of the crystal structure through the paraelectric-ferroelectric (PE-FE) transition remains ambiguous. Some reports, but not all, suggest an intermediate phase (IP) between the PE and FE phases, with IP probably also being a polar phase. Our aim is to pinpoint the exact structural evolution of this material throughout the range 300 - 1450 K., by exploiting the unique advantages of PND in determining subtle oxygen atoms displacements, together with the high flux and resolution of GEM.

Identifier
DOI https://doi.org/10.5286/ISIS.E.24067344
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24067344
Provenance
Creator Professor Phil Lightfoot; Dr Richard Goff
Publisher ISIS Neutron and Muon Source
Publication Year 2012
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2009-03-23T10:53:50Z
Temporal Coverage End 2009-07-28T04:43:12Z