Magnetic excitations in mesoporous hematite
We have recently prepared mesoporous forms of various metals oxides. In some cases the imposition of a mesostructure changes other properties of the material significantly. One example of such a change is found in mesoporous hematite (alpha-Fe2O3). The bulk material undergoes a Morin transition at 265 K from a canted antiferromagnetic structure, to another form of antiferromagnetic order with no canting. The mesoporous form shows no such transition down to 1.5 K. This transition arises from a competition between different forms of exchange and single-ion anisotropy originating from ligand-field terms. In order to explore how the mesostructure might influence this transition, we propose to perform inelastic neutron scattering measurements to determine zone-centre excitations that can be related to such terms in the Hamiltonian.
- 1 5
- 1000meV
- 100K
- 100meV
- 100mev
- 10meV
- 1100meV
- 12
- 120
- 12000meV
- 120C
- 120eV
- 125meV
- 12R
- 12eV
- 12mev
- 135meV
- 1400mev
- 150
- 150Hz
- 150K
- 150mev
- 160
- 16000meV
- 160eV
- 16eV
- 1700meV
- 17mev
- 180meV
- 180mev
- 18meV
- 1eV
- 2 494g
- 2 77g
- 20
- 200
- 20000meV
- 2000meV
- 200K
- 200mev
- 20K
- 20eV
- 222meV
- 230meV
- 230mev
- 24x45
- 250Hz
- 250meV
- 250mev
- 25mev
- 25x40
- 265
- 28000meV
- 280K
- 28eV
- 2eV
- 300Hz
- 300K
- 300meV
- 30mev
- 350Hz
- 350meV
- 350mev
- 35mev
- 36000meV
- 36eV
- 3Gd
- 3S
- 3s
- 4 6K
- 4 7K
- 4 ethynyltoluene
- 400
- 4000meV
- 400C
- 400Hz
- 40x40
- 44
- 44000meV
- 44CaO_SiO
- 44eV
- 450Hz
- 45meV
- 45mev
- 4Gd
- 4R
- 4S
- 4eV
- 50
- 500meV
- 50meV
- 50mev
- 50x40
- 50x50
- 5Gd
- 5K
- 5S
- 5x5
- 600
- 600Hz
- 600eV
- 600hZ
- 600mev
- 60mev
- 650meV
- 650mev
- 6Gd
- 6R
- 7000
- 70meV
- 720524
- 750C
- 7Gd
- 7R
- 7eV
- 80
- 80000meV
- 8000meV
- 80eV
- 80meV
- 8Gd
- 8R
- 8eV
- 8gd
- 9Gd
- 9R
- 9eV
- ALIGN
- Al
- AlH3
- C2H4
- CD3CelloBiocide
- CD3CelloBiocide D2O
- CD3CelloBiose D2O
- CD3ND3PbBr3
- CH3ND3PbBr3
- CH3NH3PbBr3
- CaTiSiO5
- Can
- CelloBiose
- CelloBiose D2O
- Chopper
- Cooling
- Cs metaborate
- Cu 04TiSe2
- Cu 06TiSe2
- Cu 08TiSe2
- CuxTi2
- CuxTiSe2
- Cysteine
- D2O D2
- D2O TDF
- D2O TDF HD
- D2O TDF nH2
- D2O TDF pH2 rich
- D2O nH2
- D2O pH2
- DCl
- DRP059
- EMPTY
- Ei 1000meV
- Ei 100meV
- Ei 10meV
- Ei 12meV
- Ei 150meV
- Ei 15meV
- Ei 250
- Ei 250meV
- Ei 25meV
- Ei 450
- Ei 45meV
- Ei 50
- Ei 50meV
- Ei 550
- Ei 550meV
- Ei 60meV
- Empty
- Emtpy
- Fe2O3
- GR
- GUM
- Gd
- GeCoO3
- GeCuO3
- H2
- H2O
- HCl
- Harrison
- He
- Hematite
- Hi H
- Hill
- Hydroxyapatite
- Hz
- Invar
- Jaws
- Lefmann
- MAPbBr3
- MONVAN
- MP89 91
- MT
- MTCan
- Mesoporous
- Mono
- NCaO_SiO2
- ND3CD3PbBr3
- ND3CH3PbBr3
- NH3CH3PbBr3
- Na2O_4SiO2
- Na2Si2O5
- NaH
- NaO4SiO2
- Ni
- Ni H
- Nim 50
- Open
- POLY
- PdO xH2O
- Poly
- Pure
- RT
- Raney
- Sc
- Sc 20 Ce
- Sc 5 Ce
- Sc pure
- Sc_pure
- SiO2
- SiO2 NAT
- SiO2 O18
- Sr3Cr2O8
- T 1 5K
- T 100K
- T 100K180mev
- T 10K
- T 112K
- T 115K
- T 120K
- T 125
- T 125K
- T 12K
- T 13
- T 137
- T 137K
- T 150
- T 150K
- T 153K
- T 160
- T 160K
- T 165K
- T 175
- T 175K
- T 185K
- T 190K
- T 20
- T 200
- T 200K
- T 200K180mev
- T 20K
- T 220K
- T 225K
- T 240K
- T 250K
- T 25K
- T 260K
- T 280K
- T 300
- T 300K
- T 30K
- T 37K
- T 38
- T 400K
- T 5
- T 50
- T 500K
- T 50K
- T 595K
- T 5K
- T 600K
- T 62K
- T 6K
- T 7
- T 75
- T 75K
- T 87K
- T 8K
- T 90K
- T cool
- T cooling
- TEST
- T_head 81K
- T_samp 1 5K
- T_samp 25K
- T_samp 2K
- T_samp 31K
- T_samp 71K
- T_samp cooling
- Toluene
- Ultrasil
- Van
- White
- ZrH2
- ZrMn2
- align_long
- alpha fe2o3
- anisotropy
- another
- antiferromagnetic
- arises
- base
- beam
- between
- bulk
- c400
- can
- canted
- canting
- cases
- cassette
- centre
- change
- changes
- check
- chopper
- competition
- cooling
- cooling100 5K
- coolingRT 5K
- d sushi
- dae
- determine
- different
- down
- dried
- dsc
- dsc 50
- eV
- ei250
- electronics
- envelope
- example
- exchange
- excitations
- explore
- f 100
- f 150
- f 200
- f 200Hz
- f 250
- f 300
- f 300Hz
- f 400
- f 400Hz
- f 600
- f 600Hz
- field
- form
- forms
- found
- hamiltonian
- hematite
- imposition
- in
- inelastic
- influence
- invar
- ion
- jasw
- jaw50x50
- jaws
- jaws 25x40
- jaws 30x50
- jaws 50x27
- jaws 50x50
- jaws15x50
- jaws25x40
- jaws45x45
- jaws50x50
- jaws5x5
- ligand
- magnetic
- mari
- material
- meV
- measurements
- mesoporous
- mesoporous alpha Fe2O3
- mesostructure
- metals
- might
- mono
- morin
- neutron
- nim 50
- no
- omega 75
- omega 75 5
- omega 76
- omega 76 5
- omega 77
- omega 77 5
- omega 78
- omega 78 5
- omega 79
- omega 79 5
- omega 80
- omega 80 5
- omega 81
- omega 81 5
- one
- open
- order
- originating
- oxides
- perform
- position
- prepared
- properties
- propose
- recently
- related
- reopen
- salt sushi
- scattering
- shows
- shutter
- significantly
- single
- some
- spec
- structure
- sushi
- terms
- test
- toluene
- transition
- under
- undergoes
- van
- various
- warming
- wet
- white
- x 08
- zone
Provenance | |
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Creator | Professor Andrew Harrison; Dr Adrian Hill; Professor Kim Lefmann |
Publisher | ISIS Neutron and Muon Source |
Publication Year | 2011 |
Rights | CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/ |
OpenAccess | true |
Contact | isisdata(at)stfc.ac.uk |
Representation | |
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Resource Type | Dataset |
Discipline | Photon- and Neutron Geosciences |
Temporal Coverage Begin | 2007-12-04T16:38:57Z |
Temporal Coverage End | 2008-07-25T21:46:06Z |