The phase stability of alpha-glycine at high pressure

DOI

Though the beta and gamma forms of the simplest amino acid, glycine, yield a variety of different phases on application of pressure, Raman data suggest that the most common alpha form of glycine persists to 20 GPa. In this experiment neutron powder diffraction data will be collected to 19 GPa, the anvil limit currently available on the PEARL instrument. This will be one of the highest pressure yet applied to an organic crystal structure. The results will enable the spectroscopic results to be tested, and provide data suitable for determination of the equation of state of alpha glycine. This will permit mechanical properties of alpha glycine to be compared to those of other phases, and the differences in phase behaviour understood in terms of the differing packing motifs which characterise their crystal structures.

Identifier
DOI https://doi.org/10.5286/ISIS.E.84424866
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/84424866
Provenance
Creator Professor Simon Parsons; Dr Craig Bull; Dr Nicholas Funnell; Professor Konstantin Kamenev; Mr Nico Giordano
Publisher ISIS Neutron and Muon Source
Publication Year 2020
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2017-02-21T10:00:00Z
Temporal Coverage End 2017-05-04T07:39:32Z