Nanogels because of their three-dimensional physical structure and tunable chemical properties as well as their stimuli-responsive nature have emerged as one of the most significant trends in nanomedicine, skin care products, cell encapsulation and many other applications. Our goal is to resolve structure of the nanogels at the buried oil-water interface. This will contribute to our current understanding of their important physic-chemical behaviours such as the transport through cell membranes and stabilisation of emulsions systems.