Structural study of the higher oxidation states of the nickel positive electrode

DOI

Although the first patents involving the nickel positive electrode are more than 100 years old, our understanding of the phases involved in this system is still not complete. As an example, only very recently the crystal structure of b-NiOOH has been determined, and turned out to not to have the same layer stacking sequence of b-Ni(OH)2, as previously believed. The aim of the proposed work is thus to extend the studies carried out by our group for the b-NiOOH phase to the gamma phase, whose exact structure is still not known. We would like to combine neutron diffraction with inelastic neutron scattering to determine the structure of a sample of HxNay(H2O)zNiO2. Understanding the details of the local proton environments and how these change in the various polymorphs is crucial to improving these materials and obtain improved nickel based batteries.

Identifier
DOI https://doi.org/10.5286/ISIS.E.24090211
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24090211
Provenance
Creator Dr Montserrat Casas Cabanas; Dr Rosa Palacin
Publisher ISIS Neutron and Muon Source
Publication Year 2016
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2013-03-19T09:36:55Z
Temporal Coverage End 2013-03-21T11:34:09Z