X-ray Raman scattering and X-ray diffraction of nitrogen up to 150 GPa

DOI

To explore the behavior of nitrogen under extreme pressures, we utilize non-resonant inelastic X-ray Raman scattering capabilities available at ID20 beamline (ESRF). With this study we aim to extend our understanding of the structural phase transitions and electronic properties of nitrogen. The prototypical diatomic molecule nitrogen shows an impressive polymorphism. Under pressure, delta-N2 undergoes several structural transitions to epsilon-, zeta- and amorphous black eta-N2 at room temperature. Our approach involves two complementary techniques - X-ray Raman scattering (XRS) and X-ray diffraction (XRD). XRS allows us to study the changes in electronic structure associated with the pressure-induced transformations in nitrogen. At the same time, XRD measurements will be used to monitor the structural changes in conjunction with subsequent AIMD simulations. We anticipate that this study will provide unique insights for materials and planetary science.

Identifier
DOI https://doi.org/10.15151/ESRF-ES-1901513211
Metadata Access https://icatplus.esrf.fr/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatplus.esrf.fr:inv/1901513211
Provenance
Creator Leonie TIPP; Mirco WAHAB ORCID logo; Peter SCHÄFER; Robin SAKROWSKI ORCID logo; Sindy FUHRMANN (ORCID: 0000-0001-5289-784X); Christoph SAHLE ORCID logo; Gordon SCHOLZ ORCID logo; Johannes NISKANEN ORCID logo; Christian STERNEMANN ORCID logo
Publisher ESRF (European Synchrotron Radiation Facility)
Publication Year 2027
Rights CC-BY-4.0; https://creativecommons.org/licenses/by/4.0
OpenAccess true
Representation
Resource Type Data from large facility measurement; Collection
Discipline Particles, Nuclei and Fields