Electron-driven solvent segregation in Li-NH3-MeNH2

DOI

We request 4 days Rapid Access on MAPS to finalise the investigations in our recent experiment, RB1710214. This experiment on phase-separated metal-amine liquids proved to be successful, but being the first time these systems have been measured on MAPS we needed to overcome a few hurdles that unfortunately resulted in data that are not-quite publishable (see experimental report for RB1710214). Nevertheless, we were extremely pleased to see that MAPS is an ideal tool for examining phase-separation in these multi-solvent systems, and believe that with 4 days further time on the instrument, this study can be completed. The interest in these systems stems from their ability to undergo a metal-insulator in the liquid phase, with an intervening region of liquid-liquid separation.

Identifier
DOI https://doi.org/10.5286/ISIS.E.86646550
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/86646550
Provenance
Creator Dr Neal Skipper; Professor Stewart Parker; Dr Chris Howard; Dr Andrew Seel; Dr Patrick Cullen
Publisher ISIS Neutron and Muon Source
Publication Year 2020
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences; Physics
Temporal Coverage Begin 2017-05-22T07:00:00Z
Temporal Coverage End 2017-06-08T08:20:27Z