Hydrogen-bond dynamics of water in C-A-S-H: insights into the hydration properties of low CO2 cements

DOI

The manufacture of every ton of cement emits approximately 0.8 tons of CO2 into the atmosphere, comprising 5-7% of the global human-made CO2 emissions. A low pH - low CO2 class of alkali activated materials consisting of a nanoscopic phase of an Al-substituted C-S-H, called C-A-S-H, is one of the most promising replacements of traditional cementitious binders. C-A-S-H has improved durability and strength properties, as well as environment-friendly character (slag recycling and reduced CO2 emission). Little is known about the atomic structure of C-A-S-H and structural and dynamical properties of water within its pores. We propose to elucidate the H-bond dynamics of water in C-A-S-H, using a protocol that allows accessing the different pores of the C-A-S-H structure. This study will be key to construct a complete picture of water structure and dynamics in the different pores of C-A-S-H.

Identifier
DOI https://doi.org/10.5286/ISIS.E.101133826
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/101133826
Provenance
Creator Dr Alejandro Fernandez Martinez; Dr Gabriel Cuello; Miss Zhanar Zhakiyeva; Dr Alexander Van Driessche; Dr Svemir Rudic; Dr Rogier Besselink; Mr Sylvain Campillo-Cressot; Dr Maria Pilar Asta Andres
Publisher ISIS Neutron and Muon Source
Publication Year 2022
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2019-03-14T09:00:00Z
Temporal Coverage End 2019-03-20T09:44:45Z