56 datasets found

The hybrid organic-inorganic perovskites are of great interest as functional materials, because they combine the well-established perovskite topology with new physics and...

We request 3 days’ beam time on POLARIS for in-situ powder diffraction studies of the reactions of lithium amide or lithium imide with manganese(IV) oxide under flowing argon or...

Ammonia is seen as a key part of the transition to a sustainable energy economy, but needs decomposition catalysts to release its stored hydrogen. Lithium nitride-hydride...

We have constructed a novel microwave frequency resonator that can sit within the GEM and POLARIS diffractometers and will allow us to simultaneously collect diffraction and...

We seek to develop new MOFs for sensing and removal of toxic gases (e.g., SO2) and request 4 days on POLARIS to study the structural binding details and dielectric data...

Cubic cadmium(II) cyanide shows the most pronounced isotropic NTE effect known, with behaviour more than twice as extreme as that of better known materials such as ZrW2O8. This...

Whilst rechargeable batteries continue to take over the consumer electronics market, they are unsuitable to replace specific battery technologies, such as the thermal battery,...

With the discovery of almost 3000 exo-planets it is clear that planet formation is a by-product of star formation, yet in the micron ? cm size range, where relative velocities...

The sequence of structural phase transitions that occur in distorted ABO3 perovskites as a function of temperature is of intrinsic interest for better understanding of the...

The objectives of this proposal is to seek 2 days on POLARIS in order to test and complete a full commissioning of the latest design of our prototype in-situ reaction cell for...

Inexpensive light-metal amides are among the most highly active and effective ammonia decomposition catalysts at modest temperatures and are likely to surpass the performance of...

In a series of in situ neutron diffraction measurements from deuterium up-take in Li3N, the present authors have identified a novel non-stoichiometric 'quasi-imide' of...

Heavy alkaline earth nitride hydrides (AE2NH, with AE = Ca and Ba) are of interest due to their potential suitability as electrolyte materials in a variety of electrochemical...

The Earth¿s climate is strongly influenced by clouds. The oxidative processing of pollutants in clouds affects cloud droplet size and optical properties, important climatic...

SrCuTe2O6 consists of a 3-dimensional arrangement of spin-1/2 Cu ions that are coupled into network of isolated triangles,a highly frustrated hyperkagome lattice consisting of...

Ammonia has been proposed as a high density chemical energy-storage media, which can be safely and reversible stored within low cost saline halides. Here we propose to extend...

Light metal amides and imides are a new class of highly active ammonia decomposition catalysts. Indeed, composites of lithium imide and transition metal nitrides are likely to...

The objective of the proposed experiment is to develop an understanding of the Li/Ni/Mn ordering in a commercially relevant lithium ion battery positive electrode,...

This proposal seeks to study three systems associated with heat-storage applications using in situ neutron powder diffraction. The first experiment will focus on a sample of...

Surfactant-silica self-assembly processes have been extensively studied since the discovery of M41S mesoporous materials in 1992. Mesoporous silicate films can be grown from...