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Application of direct inversion to magnetic contrast datasets.
We have developed an experimental approach using a buried magnetic layer to provide contrast in systems consisting of complex biomolecular layers tethered to gold surfaces. This... -
Investigation of asphaltene nanoaggregate size under conditions of CO2 reserv...
The asphaltene fraction of crude oil is defined by its solubility parameters (insoluble in n-heptanebut soluble in toluene). Changes in conditions (temperature, pressure,... -
A QENS Study of Benzyl Phenyl Ether, a Lignin Model Compound, on a Hydrodeoxy...
Bio-oil is an alternative and renewable energy from biomass, however, its high content of oxygenates result in low heating values and chemical/thermal instability. One effective... -
YMnO3-x : Mn(I) in a mixed metal oxide ?
Topotactic reduction of YMnO3 with CaH2 yields three new reduced phases. Two of these phases appear to have compositions close to YMnO2.5 but with very different anion vacancy... -
Long-range magnetism in spin, charge, and orbital ordered Pb3Mn7O15
Manganese oxides have attracted great interest in solid-state physics research owing to the diverse range of electronic ordering phenomena. Pb3Mn7O15 is a relatively... -
The first in operando INS study of a catalytic reaction: CO oxidation over PdO
Inelastic neutron scattering has been used to study adsorbed species on catalysts for more than 30 years. All of this work has one feature in common: they are all ¿snapshots¿ of... -
Proton dynamics of graphenes of different hydrogen content
Graphene is defined as a: single layer of carbon atoms with each atom bound to three neighbours in a honeycomb structure. This suggests that in a macroscopic, manageable... -
Topochemically Reduced Complex Iridium Oxides
In recent years there has been a growing interest in modifying the anion lattice of complex transition metal oxides, via topochemical manipulation, to tune the magnetic and... -
Powder diffraction studies under high deuterium pressure
The aims of the experiment are (1) to obtain structural data for the model hydrogen storage intermetallic LaNi5 under a deuterium pressure of 3000 bar at cryogenic temperatures,... -
Topotactically reduced phases containing square planar Co(II) centres
The topotactic reduction of Sr3Co2O5Cl2 and Sr3Co2O5.80 yields the Co(II) phases Sr3Co2O4Cl2 and Sr3Co2O5 respectively. These phases contain corner linked arrays of... -
Simultaneous INS and Raman spectra of centropolyindanes.
The family of centropolyindanes are created by edge-wise fusing of the cyclopentane ring of several indane units (D. Kuck, Chemical Reviews 2006, 106, 4885-4925).... -
Studies of Muon-Beam-Induced currents in semi-imsulating GaAs
This proposal is a continuation of our recent proposal RB 610004 where this partcurrent measurements) was not completed due to the reduced beam intensity. Currents experiment... -
INS studies with MAPS of Nafion and model compounds
In the archetypal hydrogenoxygen proton exchange membrane fuel cell design, a proton-conducting polymer membrane (typically Nafion) contains the electrolyte solution that... -
Spin excitations in the paramagnetic phase of a charge-ordered bilayered mang...
In a previous experiment we measured the spin wave spectrum of the half-doped bilayer manganite Pr(Ca,Sr)2Mn2O7 in its spin, charge and orbital ordered phase. The data, which... -
The crucial roles of metal-hydrogen stretches in catalytic hydrogenation on b...
Bimetallic alloy catalysts with optimized metal ratio usually exhibit a superior catalytic hydrogenation activity and selectivity compared to individual mono-metallic catalysts,... -
Magnetic structures of antiferromagnetic heavy fermion CeAuAl3 and CeCuAl3 co...
CeAuAl3 and CeCuAl3 compounds crystallize in the tetragonal I4mm, BaNiSn3-type and display interesting bulk properties. Here we propose to investigate the magnetic structures of... -
INS study of the effect of particle size on the formation of beta-palladium h...
Finely divided, supported palladium particles are used as catalysts in many technical processes. However, there is still considerable potential to improve catalyst performance... -
The chemisorption of hydrogen on cobalt
Cobalt based catalysts are widely used within industry for Fischer-Tropsch synthesis (FTS) in the production of sulphur free diesel. Despite the wide application of cobalt... -
The use of INS to characterise deactivation of methane reforming catalysts.
For the first time, the research team aim to use INS to characterise a series of candidate methane reforming catalysts. Recent studies have shown that modification of... -
The chemisorption of hydrogen over a Raney cobalt catalyst: An INS investigation
Building on a successful programme investigating aspects of iron based Fischer-Tropsch synthesis (FTS) catalysts, it is opportune to extend that work to include Co FTS...