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Determination of the H-H bond lenght of H2/CuBTC MOF (SANDALS)
The rotational line of hydrogen is very clearly measured with TOSCA. For the past few years I have noticed that the changes in the position of the rotational line do not follow... -
Determination of the Pt-H bondlengths on a Pt/C fuel cell catalyst
We have recently demonstrated that it is possible to obtain structural information about adsorbed hydrogenous species from a variety of metal catalysts. We emphasise that this... -
Influence of chemical composition on the macroscopic properties of industrial...
Our previous proposals on ceramic glazes were rejected due to the high number of chemical components listed in the proposed (industrially typical) samples. Unfortunately the... -
Protic Ionic Liquid ¿ Benzene Interactions
Ionic liquids (ILs) have been extensively studied for liquid¿liquid extractions and have recently been examined for the purification and separation of crude oil components. Of... -
The quest for attractive divalent sulfur - oxygen interactions
Weak nonbonded interactions between a divalent sulfur and an oxygen atom have attracted growing interest because of their roles in determining the structure and the biological... -
Structural comparison of peptidomimetic building blocks
Peptidomimetics are synthetic mimics of peptides, the natural building blocks of proteins, and their development is a growing field of science. An underlying theme in recent... -
Probing the Earliest Stages of Zeolite Crystallisation
Our aim is to provide new data concerning the evolution of amorphous gel phases into crystalline inorganic materials to allow information about crystallisation mechanism of... -
Structural characterization of water confined in MCM-41
By combining NDIS experiment and EPSR simulation we have been able to show with a previous experiment (RB 720500) two main phenomena for water confined in the MCM silica matrix.... -
Unraveling temperature dependent cis/trans-isomerisation in bis{(trifluoromet...
Raman spectroscopy has identified differences in how the anion conformer populations of alkali metal bis{(trifluoromethyl)sulfonyl}imide molten salts (Li-Cs) and protic... -
Neutron diffraction of amorphous iron sulfates (AFS)
Amorphous iron sulfate pentahydrate has been identified as one of the iron sulfates found on the Martian surface during the Spirit and Opportunity Rover missions in recent... -
The structure of paraquat in solution and in clay gels
This experiment will use high resolution neutron diffraction to determine for the first time thesolvation structure of the pesticide paraquat in bulk aqueous solution and in the... -
Using small angle neutron diffraction to describe the status of water in solu...
Fish oocytes and embryos are complex cryobiological objects for which, successful cryopreservation has still not been achieved. This circumstance seriously restricts the... -
Glasses and supercooled liquids in the Se-Cl system
Little is known on the structure and properties of vitreous Se doped with halogens in contrast to group III, IV, V, and VI dopants and also many metal additives. Our Raman... -
A model system to study the important interactions of proteins from extreme e...
Organisms which live in the presence of large quantities of salt are known as halophilic (meaningsalt-loving). Halophilic proteins are of great interest due to their ability to... -
Structural characterization of a synthetic peptoid monomer
Peptoids are synthetic mimics of peptides (the natural building blocks of proteins) in which the side chain is attached to the backbone amide nitrogen instead of the central... -
Local structure of polymers in confined geometries in surface dominated samples
This proposal is focused on developing an understanding of how surfaces affect the local structure of synthetic polymers. There is considerable evidence for a strong variation... -
A Total Scattering Study of Dopamine, L-DOPA and Norepinephrine Aqueous Solut...
We request 5 days on Sandals to study the interactions of the neurotransmitters dopamine, L-dihydroxyphenylalanine and norepinephrine in aqueous solution. The interactions of... -
The structure of ammonia borane in water, DMSO and THF
There is an increasing urgency to find stable and lightweight hydrogen storage materials for clean transport applications. Promising options being investigated include Mg-based... -
The structure of aprotic and aromatic solvents
In this proposal we would like to study the structure of polar aprotic and aromatic liquids using H/D and 15N/*N isotopic labelling on SANDALS. The molecules chosen for study... -
Neutron diffraction of amorphous calcium carbonate (resubmission)
Amorphous calcium carbonate (ACC) is a transient phase in one of the most important biomineralisation systems in animals (s.g.) such as crustaceans. The literature reports many...