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Observation of low energy modes of adsorbed CO on a catalyst
Carbon monoxide occurs widely in industry in many roles. It is a feedstock for methanol synthesis and in Fischer-Tropsch chemistry for synthetic petrol and diesel. It is a... -
Discriminating adsorption sites in the coordinatively unstaurated 3d metal io...
Using chemically different substances as co-adsorbates allows one to block certain types of adsorption sites in a given porous material or even on a surface. This can be very... -
SANS Study of the interaction of non-ionic surfactants with wheat and barley ...
We propose to make use of SANS to determine the influence the presence of cuticular plant waxes have on the size, shape and structural properties of various non-ionic... -
Condensation of supercritical hydrogen in nanoporous hydrogen storage materia...
This proposal builds on the success of our last INS experiment (RB1210041), which used TOSCA's new low energy capabilities to access and track the elastic line as well as the... -
The structure of hydrogen in calcium-ammonia-graphite: an in situ time resolv...
The aim of this proposal is to determine the in-plane and out-of-plane structure of H2 in the two dimensional galleries of stage-I calcium-ammonia-graphite intercalates: this... -
Neutron Compton scattering investigation of hydrogen defects in Al2O3/Al hydr...
The need for structural materials that can resist hydrogen assisted degradation becomes critical for the continuation of the development of the hydrogen economy. Understanding... -
Probing the interaction of hydrogen with supported gold nanoparticles
Small gold nanoparticles (1-5 nm) supported on metal oxides are extremely active catalysts for C-C coupling, aerobic oxidations and selective hydrogenations. The interaction of... -
Hydrogen in the breeding blanket materials for fusion reactors: A new insight...
Pb-Li alloy (Li 15.7-16.7at.%) is a candidate as tritium breeding blanket material for fusion reactors. Despite the extensive work reported in literature, the values of the... -
Investigation of hydrogen/nickel and hydrogen/cobalt interactions in new meta...
Raney-nickel type catalysts are some of the most versatile technical agents for efficient hydrogenation reactions. Raney-type catalysts based on Fe, Co, Ru and other metals have... -
Uptake of Molecular Hydrogen by High-performance Carbon Nanostructures (IRIS)
High sorption capacities and enhanced interaction strengths are the two most fundamental prerequisites for the deployment of carbon-based materials as hydrogen-storage media. In... -
INS examination of potential hydrogen spillover on pure and metal decorated m...
Metal oxides(MO) are widely used in technological applications especially for catalysts and supports for catalysts. We propose to use the inelastic response of H2 adsorbed on... -
Magnetic excitations in mesoporous hematite
We have recently prepared mesoporous forms of various metals oxides. In some cases the imposition of a mesostructure changes other properties of the material significantly. One... -
SANS Study of the interaction of reconstituted model wheat waxes with non-ion...
The understanding of the plant wax-surfactant interaction process is crucial to the development of more effective pesticide and fungicide formulations, essential for improving... -
Exploration of the microscopic origins of thermal anomalies observed in molec...
It is a well established fact that several molecular liquids experiences a series of thermal anomalies as measured by microscopic and macroscopic techniques. A remarkable case... -
Hydrogenation of frustrated Lewis pairs in solution
It has been postulated that 'Frustrated Lewis Pairs' react after associating in an encounter complex held by dispersion forces, and that is it is this complex that interacts,... -
Lattice vibrations of hydrogen impurities in a solid neon matrix
In recent incoherent inelastic neutron scattering experiments we have shown that the anharmonic single-particle dynamics of H2 can be measured with high precision in quantum... -
Hydrogen storage: interaction between hydrogen and lithium nitride at high pr...
We apply for beam time on TOSCA to investigate this highly unusual system. Lithium nitride appears unique among storage materials in its ability to take up significant amounts... -
Determination of the H-H bond lenght of H2/CuBTC MOF (SANDALS)
The rotational line of hydrogen is very clearly measured with TOSCA. For the past few years I have noticed that the changes in the position of the rotational line do not follow... -
The Dynamics of Molecular Hydrogen in Synthetic Clays
In this proposal we aim to study the low temperature uptake and dynamics of hydrogen in the interlayer region of partially hydrated pillared clays. There are linked dual... -
Determination of the Pt-H bondlengths on a Pt/C fuel cell catalyst
We have recently demonstrated that it is possible to obtain structural information about adsorbed hydrogenous species from a variety of metal catalysts. We emphasise that this...