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Programme Access Rosseinsky
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Phase Separation and Jahn Teller Distortion in Molybdate Perovskites
Two days of beamtime on HRPD will be used to examine a family of double perovskites Sr2YbMO6 that are isostructural at room temperature. When M = Mo5+ the monoclinic perovskite... -
Uptake of Molecular Hydrogen by High-performance Carbon Nanostructures (IRIS)
High sorption capacities and enhanced interaction strengths are the two most fundamental prerequisites for the deployment of carbon-based materials as hydrogen-storage media. In... -
Structural strudy of deuterated acetone
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Quantum dynamics in a J_eff=1/2 isotropic triangular-lattice antiferromagnet
This proposal is part of our research programme to explore the spin dynamics of strongly-frustrated quantum antiferromagnets. A canonical model system is the spin-1/2 triangular... -
Determining the Crystal and Magnetic Structures of [Li(oxalate)]2[Co5(OH)8]
Dense corrdination frameworks that contain inorganic centres connected into extended lattices by polyatomic anions often adopt highly anisotropic structures. Thus they often... -
Understanding the formation of diamonds: Calibrating the coesite solid-inclus...
Diamonds provide our only direct samples of the very deep Earth and understanding their origin is consequently of great interest to Earth Scientists. The origin of diamonds can... -
The Dynamics of Molecular Hydrogen in Synthetic Clays
In this proposal we aim to study the low temperature uptake and dynamics of hydrogen in the interlayer region of partially hydrated pillared clays. There are linked dual... -
Hydrogen Uptake by Pillared Graphite Oxides
High sorption capacities and enhanced interaction strengths are the two most fundamental prerequisites for the deployment of carbon-based materials as hydrogen-storage media. In... -
What is the Room Temperature Structure of NaTaO3?
The current proposal seeks to establish the origin of t non-perovskite-like peak splitting observed in HRPD data for NaTaO3. It is our hypothesis that this is a result of the... -
What is the Room Temperature Structure of NaTaO3?
The current proposal seeks to establish the origin of t non-perovskite-like peak splitting observed in HRPD data for NaTaO3. It is our hypothesis that this is a result of the... -
Diffusional Dynamics of Molecular Hydrogen Bound to Carbon Nanohorns
The present experiment aims to elucidate the energetics and geometry of translational diffusive motions exhibited by molecular hydrogen bound to carbon nanohorns. Previous... -
CaTiO3 cooling from 291 K 30-130 ms jaws 15*20
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Dynamics of poly-acrylonitrile in polymer-layered silicate micro-objects
We propose to measure vibrational spectra from poly-acrylonitrile confined in nanoporous silica matrixes. Polymers confined in silica have recently been the subject of great... -
Investigation of the correlations above TN in PdCrO2
In recent years there has been a large interest in geometrically frustrated magnetic systems, especially those with spins interacting on two-dimensional triangular lattices... -
Competing degenrate magnetic states in Ba1-xNaxFe2As2
Magnetic and superconducting ground states have been proposed to coexist in a relatively narrow compositional range in the so-called 122 pnictide superconductors. We recently... -
High resolution neutron diffraction study to investigate quadrupolar ordering...
Recently we have investigated magnetic and quadrupolar ordered states of YbRu2Ge2 using zero-field muon spin relaxation (µSR), neutron diffraction and inelastic neutron... -
Unusual higher order incommensurate components in the magnetic structure of TmCu
This proposal forms a very specific part of our project to investigate complex magnetic structures in rare earth intermetallics. In extensive bulk measurements on high purity... -
Polycarbonate and tetramethyl bisphenol A polycarbonate
The miscibility of polycarbonates (PC) with polystyrene (PS) appears to be closely related to chain dynamics. Among all polycarbonates, tetramethyl bisphenol-A polycarbonate... -
The effect of redox on the substitution mechanism of Ti in meteoritic hibonite
We request 3 days of beam-time on HRPD to identify the substitution mechanism of Ti3+ and Ti4+ in synthetic hibonites [CaAl12O19]. The experiment forms part of a larger...
