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Structral characterisation of a novel lead free perovskite layer structure an...
Lead free antiferroelectric materials are the focus of much attention for the replacement of lead based materials in electronic devices, such as high energy storage capacitors,... -
The XY pyrochlore AFM:spin dynamics upon rare-earth dilution in Er2Ti2O7 (CON...
Er2Ti2O7 constitutes an experimental realization of the <111> easy-plane pyrochlore AFM and orders at 1.1 K into the theoretically predicted spin structure. However, the... -
Impact of Jahn-Teller Distortions in Sr0.5Pr0.5MnO3
We propose to use the HRPD to establish the sequence of structures, and the nature of the transitions between these, in two complex manganites Sr0.5Pr0.5MnO3 and... -
Structural study of liquid Ge-Sb-Te alloys
Ge-Sb-Te chalcogenide alloys are important for applications in advanced (non-volatile) random-access memory based on a reversible switching between the crystalline and amorphous... -
Copy of: Division of the supercritical fluid state into liquid- and gas-like ...
In recent years, the long-standing belief that beyond the critical point, matter exhibits no clear transition between liquid-like and gas-like states has been questioned. A line... -
Parameterisation of the crystal structures of tilted perovskite phases with s...
The physical properties of the perovskite family remain an enduring topic in solid state research. In this proposal we aim to study the solid state structural phase transitions... -
Structural phase transitions in ferroelectric layered perovskite oxides
Recent theoretical work has identified that oxygen octahedral rotations (OORs) in layered perovskites such as RuddlesdenPopper (RP) phases A2[An-1BnO3n+1] can generate... -
Simultaneous Microwave Dielectric Spectroscopy and Neutron Diffraction Measur...
Ammonia has been proposed as a high density chemical energy-storage media, which can be safely and reversible stored within low cost saline halides. Here we propose to extend... -
Hydrogen from ammonia using lithium imide metal nitride composites
Light metal amides and imides are a new class of highly active ammonia decomposition catalysts. Indeed, composites of lithium imide and transition metal nitrides are likely to... -
Crystal structure and phase transitions of Sr2IrO4
Sr2IrO4 is an important material in the field of condensed matter physics, being a proposed J_eff=1/2 Mott insulator. Recent publications have shown that the reported low- and... -
Structural studies of thermochemical and phase-change naterials for heat storage
This proposal seeks to study three systems associated with heat-storage applications using in situ neutron powder diffraction. The first experiment will focus on a sample of... -
The hypersensitivity of the water phase diagram to ammonium fluoride doping
Water displays a highly complex phase diagram that is key to a range of critical processes, from the evolution of icy moons to that of the Earth's hydrosphere and even of life... -
Structural evolution and negative thermal expansion of Sr2IrO4
Sr2IrO4 is an important material in condensed matter physics, displaying a novel Jeff=½ Mott insulating state and being a rare comparative system for understanding the high... -
Gas condensation and fluid behaviour in nanoporous ZIF-8 materials upon gate...
This proposal aims to study condensation transitions in nanoporous flexible materials by means of wide Q-range neutron diffraction. We plan to perform an in-situ gas... -
IN-SITU NEUTRON DIFFRACTION STUDIES OF METAL-HYDRIDE HYDROGEN STORAGE MATERIALS
Recently [RB 900007], we have demonstrated that it is possible to determine the detailed site-by-site behaviour of hydrogen during in-situ absorption and desorption in metal... -
In-situ neutron powder diffraction studies of non-stoichiometry in Na battery...
We request 3 days on POLARIS to study the detailed crystal structure of a sodium battery cathode material that is currently under consideration for use in commercial sodium... -
Thermal expansion of kyanite, andalusite and sillimanite
Al2SiO5 forms three naturally-occurring polymorphs, kyanite, andalusite and sillimanite. These minerals are produced by varying degrees of metamorphism of sedimentary rocks, the... -
Investigation of the multiferroic materials Ba3Dy2GaNb9O30 and Ba3.5Dy2Ga1.5N...
We have recently performed a ZF muon experiment on Ba3Dy2GaNb9O30 in EMU under the influence of electric fields and demonstrated that this material demonstrates multiferroic... -
Strain/order parameter coupling and anomalous elastic properties of Sr(Ti,Zr)...
HRPD data will be collected in situ at low and high temperatures from perovskites belonging to the Sr(ZrxTi1-x)O3 solid solution which have recently been characterised for their... -
Probing the structure of calcium silicates over a wide range of length scales.
Sol-gel derived calcium silicates are of great importance due to their ability to bond to bone and stimulate new bone growth. Diffraction has revealed the atomic-scale changes...