Magnetic Excitations of a novel 2D honeycomb MOF

DOI

Materials with magnetic interactions between their metal centres play a tremendous role in modern technologies and can exhibit unique physical phenomena. The inability of traditional magnetic compounds to realise optimal material parameters or embody model hamiltonians has resulted in attention being turned to metal-organic frameworks (MOFs), which present a versatile platform for the realization of complex magnets due to their molecular building-block nature. (Me2NH2)2[Fe2L3]·2H2O·6DMF Is a novel system with Fe(III) ions in a perfect honeycomb lattice, where in-situ reduction of the ligands increases Tc from 80 to 150K, whilst preserving the crystallinity and structure. We wish to investigate the magnetic excitations of the Fe compound, and we will also synthesise a Ru(III) analogue and measure it in addition. This is combined with another proposal studying the magnetic structure.

Identifier
DOI https://doi.org/10.5286/ISIS.E.RB1910453-1
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/103213956
Provenance
Creator Dr Duc Le; Professor Andrew Goodwin; Mr Philip Welch; Dr Andrew Princep
Publisher ISIS Neutron and Muon Source
Publication Year 2022
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Natural Sciences; Physics
Temporal Coverage Begin 2019-06-23T07:00:00Z
Temporal Coverage End 2019-06-24T07:00:00Z