An investigation into the magneto - crystal field - lattice coupling in the hexagonal perovskite Ba3NdRu2O9

DOI

Ba3NdRu2O9 is an intriguing material exhibiting a structural phase transition at 110 K, an independent ordering of the Nd (25 K, FM,T1 ) and Ru (18, AFM,T2 ) magnetic sublattices, spin reorientation (Nd, AFM canting, 18 K) and an accompanying structural phase transition. The structural phase transition at 110K appears to occur as a result of single ion effects associated with the crystal field levels of Nd3+. These effects see a reversal at the magnetic ordering transition T1 where the degeneracy of the Kramers doublet ground state of Nd3+ is raised by the breaking of time reversal symmetry. The unusually strong coupling of the crystal field levels to the lattice, and their response to the magnetic ordering, represent a new mechanism for achieving a strong coupling between magnetic and structural degrees of freedom. We request 4 days on MARI to study the crystal field excitations.

Identifier
DOI https://doi.org/10.5286/ISIS.E.59897708
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/59897708
Provenance
Creator Mr Francis Wallington; Dr Chris Stock; Dr Mark Senn; Dr Angel Arevalo Lopez; Professor Paul Attfield
Publisher ISIS Neutron and Muon Source
Publication Year 2017
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences; Physics
Temporal Coverage Begin 2014-07-14T23:00:00Z
Temporal Coverage End 2014-07-16T23:00:00Z