Understanding the spin-Peierls Transition in KTCNQ and derivatives
Motivated by work showing that magnetic coupling between TCNQ anions in potassium TCNQ (KTCNQ) can be changed simply by changing the aromatic substituents, we seek to qunatify this behaviour. This can be achieved by different levels of fluorination on the quinodial ring and we would study the series TCNQ, TCNQF, TCNQF2 and TCNQF4, where there is an increasing number of F atoms substituted on the ring through the series itself. There has already been shown to be a shift between the muon-radical hyperfine coupling between TCNQ and TCNQF4 however more work is needed to be able to understand how this shift varies and whether we can in fact control the distrobution of spin density across the molecule. It is hoped this will then provide vital infomation as the the non-linearity of the way the transition temeprature depneds on F substitution.
- 100
- 20
- ALC
- Chemistry
- DCM
- F 0 0
- F 10000
- F 10010
- F 10020
- F 10030
- F 10040
- F 10050
- F 10060
- F 10070
- F 10080
- F 10090
- F 1010
- F 10100
- F 10110
- F 10120
- F 10130
- F 10140
- F 10150
- F 10160
- F 10170
- F 10180
- F 10190
- F 10200
- F 1025
- F 1040
- F 1055
- F 1064 44016770072
- F 1070
- F 1085
- F 11 9432151166049
- F 1100
- F 1115
- F 1130
- F 1145
- F 1160
- F 1175
- F 1190
- F 1205
- F 1220
- F 1235
- F 1250
- F 1265
- F 1280
- F 1295
- F 1300
- F 1315
- F 1330
- F 134 005077645288
- F 1345
- F 1360
- F 1375
- F 1390
- F 1405
- F 1420
- F 1435
- F 1450
- F 1465
- F 1480
- F 14900
- F 14910
- F 14920
- F 14930
- F 14940
- F 1495
- F 14950
- F 14960
- F 14970
- F 14980
- F 14990
- F 15000
- F 15010
- F 15020
- F 1503 56170088181
- F 15030
- F 15040
- F 15050
- F 15060
- F 15070
- F 15080
- F 15090
- F 1510
- F 15100
- F 15110
- F 15120
- F 15130
- F 15140
- F 15150
- F 15160
- F 15170
- F 15180
- F 15190
- F 15200
- F 1525
- F 1540
- F 1555
- F 1570
- F 1585
- F 16 8702397557104
- F 1600
- F 1615
- F 1630
- F 1645
- F 1660
- F 1675
- F 168 702397557104
- F 1687 02397557104
- F 1690
- F 1705
- F 1720
- F 1735
- F 1750
- F 1765
- F 1780
- F 1795
- F 1810
- F 1825
- F 1840
- F 1855
- F 1870
- F 1885
- F 189 287203344057
- F 1900
- F 1915
- F 1930
- F 1945
- F 1960
- F 1975
- F 1990
- F 2
- F 2 0
- F 20
- F 20 0
- F 2005
- F 2020
- F 2035
- F 2050
- F 2065
- F 2080
- F 2095
- F 2110
- F 2123 83735315241
- F 2125
- F 2140
- F 2155
- F 2170
- F 2185
- F 2200
- F 2215
- F 2230
- F 2245
- F 2260
- F 2275
- F 2290
- F 23 8298470417284
- F 2305
- F 2320
- F 2335
- F 2350
- F 2365
- F 2380
- F 2395
- F 2410
- F 2425
- F 2440
- F 2455
- F 2470
- F 2485
- F 2500
- F 2515
- F 2530
- F 2545
- F 2560
- F 2575
- F 2590
- F 2605
- F 2620
- F 2635
- F 2650
- F 2665
- F 267 375281440123
- F 2680
- F 2695
- F 2700
- F 2702
- F 2704
- F 2706
- F 2708
- F 2710
- F 2712
- F 2714
- F 2716
- F 2718
- F 2720
- F 2722
- F 2724
- F 2726
- F 2728
- F 2730
- F 2732
- F 2734
- F 2736
- F 2738
- F 2740
- F 2742
- F 2744
- F 2746
- F 2748
- F 2750
- F 2752
- F 2754
- F 2756
- F 2758
- F 2760
- F 2762
- F 2764
- F 2766
- F 2768
- F 2770
- F 2772
- F 2774
- F 2776
- F 2778
- F 2780
- F 2782
- F 2784
- F 2786
- F 2788
- F 2790
- F 2792
- F 2794
- F 2796
- F 2798
- F 2800
- F 2802
- F 2804
- F 2806
- F 2808
- F 2810
- F 2812
- F 2814
- F 2816
- F 2818
- F 2820
- F 2822
- F 2824
- F 2826
- F 2828
- F 2830
- F 2832
- F 2834
- F 2836
- F 2838
- F 2840
- F 2842
- F 2844
- F 2846
- F 2848
- F 2850
- F 2852
- F 2854
- F 2856
- F 2858
- F 2860
- F 2862
- F 2864
- F 2866
- F 2868
- F 2870
- F 2872
- F 2874
- F 2876
- F 2878
- F 2880
- F 2882
- F 2884
- F 2886
- F 2888
- F 2890
- F 2892
- F 2894
- F 2896
- F 2898
- F 29 9999999999999
- F 2900
- F 299 999999999999
- F 3 0
- F 3000 0
- F 3110 0
- F 33 6605536290588
- F 377 677623538249
- F 4 23761263386826
- F 4050
- F 4052
- F 4054
- F 4056
- F 4058
- F 4060
- F 4062
- F 4064
- F 4066
- F 4068
- F 4070
- F 4072
- F 4074
- F 4076
- F 4078
- F 4080
- F 4082
- F 4084
- F 4086
- F 4088
- F 4090
- F 4092
- F 4094
- F 4096
- F 4098
- F 4100
- F 4102
- F 4104
- F 4106
- F 4108
- F 4110
- F 4112
- F 4114
- F 4116
- F 4118
- F 4120
- F 4122
- F 4124
- F 4126
- F 4128
- F 4130
- F 4132
- F 4134
- F 4136
- F 4138
- F 4140
- F 4142
- F 4144
- F 4146
- F 4148
- F 4150
- F 4152
- F 4154
- F 4156
- F 4158
- F 4160
- F 4162
- F 4164
- F 4166
- F 4168
- F 4170
- F 4172
- F 4174
- F 4176
- F 4178
- F 4180
- F 4182
- F 4184
- F 4186
- F 4188
- F 4190
- F 4192
- F 4194
- F 4196
- F 4198
- F 4200
- F 4202
- F 4204
- F 4206
- F 4208
- F 4210
- F 4212
- F 4214
- F 4216
- F 4218
- F 4220
- F 47 5467957738334
- F 4870
- F 4872
- F 4874
- F 4876
- F 4878
- F 4880
- F 4882
- F 4884
- F 4886
- F 4888
- F 4890
- F 4892
- F 4894
- F 4896
- F 4898
- F 4900
- F 4902
- F 4904
- F 4906
- F 4908
- F 4910
- F 4912
- F 4914
- F 4916
- F 4918
- F 4920
- F 4922
- F 4924
- F 4926
- F 4928
- F 4930
- F 4932
- F 4934
- F 4936
- F 4937
- F 4938
- F 4939
- F 4941
- F 4943
- F 4945
- F 4947
- F 4949
- F 4951
- F 4953
- F 4955
- F 4957
- F 4959
- F 4961
- F 4963
- F 4965
- F 4967
- F 4969
- F 4971
- F 4973
- F 4975
- F 4977
- F 4979
- F 4981
- F 4983
- F 4985
- F 4987
- F 4989
- F 4991
- F 4993
- F 4995
- F 4997
- F 4999
- F 5 33483823011676
- F 5 98578694490663
- F 5001
- F 5003
- F 5005
- F 5007
- F 5009
- F 5011
- F 5013
- F 5015
- F 5017
- F 5019
- F 5021
- F 5023
- F 5025
- F 5027
- F 5029
- F 5031
- F 5033
- F 5035
- F 5037
- F 5039
- F 5041
- F 5043
- F 5045
- F 5047
- F 5049
- F 53 3483823011676
- F 533 483823011676
- F 67 1616341570501
- F 753 565929452874
- F 8 45514879379336
- F 800
- F 815
- F 830
- F 845
- F 860
- F 875
- F 890
- F 9 48683298050513
- F 905
- F 920
- F 935
- F 94 8683298050513
- F 948 683298050513
- F 950
- F 965
- F 980
- F 9800
- F 9810
- F 9820
- F 9830
- F 9840
- F 9850
- F 9860
- F 9870
- F 9880
- F 9890
- F 9900
- F 9910
- F 9920
- F 9930
- F 9940
- F 995
- F 9950
- F 9960
- F 9970
- F 9980
- F 9990
- Materials
- Physics
- Slits
- Solid
- T 100
- T 150
- T 150 0
- T 200
- T 250
- T 280 0
- T 296 0
- T 298 0
- T 299 0
- T 300
- T 300 0
- T 350
- T 50
- T 50 0
- TCNQF4
- TCNQF4_DCM
- TCNQ_DCM
- THF
- amylene
- cell
- checking
- cm 2
- continuing
- foil
- impurity
- loaded
- mg
- new
- powder
- purity
- sample
- silver
- solid
Provenance | |
---|---|
Creator | Dr Marek Szablewski; Dr Francis Pratt; Dr Stephen Cottrell; Dr Adam Berlie |
Publisher | ISIS Neutron and Muon Source |
Publication Year | 2020 |
Rights | CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/ |
OpenAccess | true |
Contact | isisdata(at)stfc.ac.uk |
Representation | |
---|---|
Resource Type | Dataset |
Discipline | Chemistry; Natural Sciences; Physics |
Temporal Coverage Begin | 2017-12-15T09:00:00Z |
Temporal Coverage End | 2017-12-19T10:34:30Z |