Structural changes in a non-covalent open porous framework - ionic liquid electrode in operando conditions

DOI

The aim of this project is to understand the influence of an applied electric potential on the structure of a porous non-covalent network-based electrode in the presence of an ionic liquid electrolyte using in-situ small angle scattering. Cucurbit[n]urils, or nano-pumpkins, are the porous network of interest in this project. Depending on the guest confined molecule, these systems are ideal candidates for developing advanced dye sensitized solar cells (DSSCs) or high power supercapacitors. Direct experimental studies of the structural changes that occur due to voltage cycling are lacking. This project with investigate ion intercalation, crystallization and nanostructured framework growth; these topics are crucial for understanding energy storage and conversion processes.

Identifier
DOI https://doi.org/10.5286/ISIS.E.61785438
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/61785438
Provenance
Creator Dr Jose Leo Banuelos; Professor Carlos Cabrera; Professor Pasquale Fulvio; Dr Richard Heenan
Publisher ISIS Neutron and Muon Source
Publication Year 2018
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences; Physics
Temporal Coverage Begin 2015-07-22T08:00:00Z
Temporal Coverage End 2015-07-24T14:27:09Z