ExoMol line list for HCN and HNC

A revised rotation-vibration line list for the combined hydrogen cynanide (HCN)/hydrogen isocyanide (HNC) system is presented. The line list uses ab initio transition intensities calculated previously (Harris et al., 2002ApJ...578..657H) and extensive datasets of recently measured experimental energy levels. The resulting line list has significantly more accurate wavelengths than previous ones for these systems. An improved value for the separation between HCN and HNC is adopted leading to an approximately 25% lower predicted thermal population of HNC as a function of temperature in the key 2000 to 3000K region. Temperature-dependent partition functions and equilibrium constant are presented. The line lists are validated by comparison with laboratory spectra and are presented in full as supplementary data to the article and at www.exomol.com.

Identifier
Source https://dc.g-vo.org/rr/q/lp/custom/CDS.VizieR/J/MNRAS/437/1828
Related Identifier https://cdsarc.cds.unistra.fr/viz-bin/cat/J/MNRAS/437/1828
Related Identifier http://vizier.cds.unistra.fr/viz-bin/VizieR-2?-source=J/MNRAS/437/1828
Metadata Access http://dc.g-vo.org/rr/q/pmh/pubreg.xml?verb=GetRecord&metadataPrefix=oai_b2find&identifier=ivo://CDS.VizieR/J/MNRAS/437/1828
Provenance
Creator Barber R.J.; Strange J.K.; Hill C.; Polyansky O.L.; Mellau G.,Yurchenko S.N.; Tennyson J.
Publisher CDS
Publication Year 2014
Rights https://cds.unistra.fr/vizier-org/licences_vizier.html
OpenAccess true
Contact CDS support team <cds-question(at)unistra.fr>
Representation
Resource Type Dataset; AstroObjects
Discipline Astrophysics and Astronomy; Interdisciplinary Astronomy; Natural Sciences; Observational Astronomy; Physics