SI file, column chemistry and mass spectrometry details (ABF decomposition)

DOI

The data are related to an ammonium-bifluoride-based rock digestion procedure. Table S1/S2 describe ion exchange chemistry procedures for hafnium, strontium and neodymium separations and purifications using micro-columns filled with AG-50W-X8 (Sr) and Ln (Hf-Nd) resins. Table S4/S4 provide information on a procedure of amplifier gain calibrations using a combination of 10(13) Ohm amplifiers for masses 172-176, as applied on the JMC-475 hafnium isotopic standard, and calculated gain factors for each measurement cycle. Table S5 lists data of calculated blank contributions for 5 USGS geological rock reference materials (GRMs), including AGV-2, BCR-2, GSP-2, RGM-2 and STM-2, based on measured total chemistry blanks and elemental concentrations of the GRMs.

The data uploaded are related to an ammonium-bifluoride-based rock digestion procedure.Figure S1 shows the different columns and packing used in ion exchange chemistryFigure S2 displayes evolution curves for Hf-Sr-Nd separations.Table S1 describes elution scheme for Hf-Sr-Nd separations and further Hf purification using micro-columns filled with AG-50W-X8 (Hf-Sr-Nd) and Ln (Hf) resinsTable S2 describes ion exchange chemistry procedures for strontium and neodymium purifications using micro-columns filled with AG-50W-X8 (Sr) and Ln (Nd) resins.Table S3/S4 provide information on a procedure of amplifier gain calibrations using a combination of 10(13) Ohm amplifiers for masses 172-176, as applied on the JMC-475 hafnium isotopic standard, and calculated gain factors for each measurement cycle.Table S5 lists data of calculated blank contributions for 5 USGS geological rock reference materials (GRMs), including AGV-2, BCR-2, GSP-2, RGM-2 and STM-2, based on measured total chemistry blanks and elemental concentrations of the GRMs.

Identifier
DOI https://doi.org/10.1594/PANGAEA.924619
Related Identifier IsSupplementTo https://doi.org/10.1002/rcm.9081
Metadata Access https://ws.pangaea.de/oai/provider?verb=GetRecord&metadataPrefix=datacite4&identifier=oai:pangaea.de:doi:10.1594/PANGAEA.924619
Provenance
Creator Újvári, Gábor ORCID logo; Klötzli, Urs ORCID logo; Horschinegg, Monika; Wegner, Wencke ORCID logo; Hippler, Dorothee; Kissel, Catherine; Palcsu, László
Publisher PANGAEA
Publication Year 2020
Rights Creative Commons Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Representation
Resource Type Dataset
Format application/zip
Size 1.1 MBytes
Discipline Chemistry; Natural Sciences