Persistent Ambipolar Heptacenes and Their Redox Species [Data]

DOI

Research Data associated with the related publication.

Sixfold TIPS-ethynylation combined with fourfold bromination of the armchair edges furnishes a long-lived, soluble heptacene; π-extension via Stille coupling accesses a persistent tetrabenzononacene. Both types of acenes were stabilized best by double TIPS-ethynylation on every other benzene ring. Tetrabromoheptacene is an ambipolar transistor material (up to 0.036 cm2/Vs n channel), which was corroborated by generation of its monoanion and monocation.

Identifier
DOI https://doi.org/10.11588/data/CVD7WF
Related Identifier https://doi.org/10.1002/anie.202200918
Metadata Access https://heidata.uni-heidelberg.de/oai?verb=GetRecord&metadataPrefix=oai_datacite&identifier=doi:10.11588/data/CVD7WF
Provenance
Creator Zeitter, Nico; Hippchen, Nikolai; Maier, Steffen; Rominger, Frank; Freudenberg, Jan; Bunz, Uwe H. F.; Dreuw, A
Publisher heiDATA
Contributor Lambert, Holger
Publication Year 2022
Funding Reference DFG: SFB1249
Rights info:eu-repo/semantics/openAccess
OpenAccess true
Contact Lambert, Holger (Universität Heidelberg)
Representation
Resource Type Dataset
Format application/zip
Size 95134812
Version 1.0
Discipline Chemistry; Natural Sciences