Crystal structure compression of polycyclic arene-perfluoroarene co-crystals and pressure-induced polymer formation

DOI

We propose to study the structural compression and pressure-induced polymerization of 1:1 co-crystals of polycyclic arenes (naphthalene, anthracene, and tetracene) and perfluoroarenes (perfluoroanthracene) using single-crystal X-ray diffraction. The aim of this experiment is to verify the postulated high pressure-stability of these compounds, which form pi-stacks of alternating non- and perfluorinated molecules in the crystal structure, and to contribute to the understanding of the design of novel carbon materials via application of supramolecular synthons such as the arene–perfluoroarene interaction and via variation of the number of aromatic rings of the molecules.

Identifier
DOI https://doi.org/10.15151/ESRF-ES-514011111
Metadata Access https://icatplus.esrf.fr/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatplus.esrf.fr:inv/514011111
Provenance
Creator Davide COMBONI ORCID logo; Alexandra FRIEDRICH ORCID logo; Krzysztof RADACKI ORCID logo; Johannes Heinrich KREBS ORCID logo; Wolfgang MORGENROTH ORCID logo
Publisher ESRF (European Synchrotron Radiation Facility)
Publication Year 2024
Rights CC-BY-4.0; https://creativecommons.org/licenses/by/4.0
OpenAccess true
Representation
Resource Type Data from large facility measurement; Collection
Discipline Particles, Nuclei and Fields