Highly branched isoprenoids in lake photic zone water

DOI

Diatom-derived highly branched isoprenoids (HBIs) are found extensively in marine sediments, but are observed in a limited number of lake sediments. To expand on this record, between 2022 and 2024, we collected lake surface sediment samples from 50 lakes in the United States of America from the Midwest and Northeast. Studied lakes capture a range in climate, water chemistry (e.g., pH, salinity, alkalinity), size, and trophic states. Lakes also vary in their diatom species compositions. Water samples from the photic zone were collected using an integrated water sampler. The integrated sample was designed to collect the water from the euphotic zone where phytoplankton are concentrated. Water was sampled from the euphotic zone (calculated as 2 times the Secchi disk depth) using an integrated water sampler fabricated from a 2 m long x 5.2 cm ID PVC pipe (2" nominal schedule 40 PVC pipe) fitted with a ball valve at the top. When the euphotic zone was >2 m, only the upper 2 m was sampled. When the euphotic zone intersected with the sediment/water interface, water was collected from the surface to 0.5 m above the sediment/water interface. Waters were filtered first through 1000 µm mesh filter and then onto a 0.7 µm glass fiber filter. Filters were extracted and analyzed by gas chromatography mass spectrometry.

Identifier
DOI https://doi.pangaea.de/10.1594/PANGAEA.979616
Related Identifier IsPartOf https://doi.pangaea.de/10.1594/PANGAEA.979496
Metadata Access https://ws.pangaea.de/oai/provider?verb=GetRecord&metadataPrefix=datacite4&identifier=oai:pangaea.de:doi:10.1594/PANGAEA.979616
Provenance
Creator Diefendorf, Aaron F ORCID logo; Dietrich, Watts; Naake, Hans H; Lowell, Thomas V ORCID logo; Corcoran, Megan C ORCID logo
Publisher PANGAEA
Publication Year 2025
Funding Reference American Chemical Society https://doi.org/10.13039/100005300 Crossref Funder ID PRF-60163-ND2 Environmental and Thermal Controls on Diatom Highly Branched Isoprenoids for Oil-Source Rock Correlation; National Science Foundation https://doi.org/10.13039/100000001 Crossref Funder ID EAR-2039795 https://www.nsf.gov/awardsearch/showAward?AWD_ID=2039795 Collaborative Research: Tapping an unused biomarker for insights of past evaporation
Rights Creative Commons Attribution 4.0 International; Data access is restricted (moratorium, sensitive data, license constraints); https://creativecommons.org/licenses/by/4.0/
OpenAccess false
Representation
Resource Type Dataset
Format text/tab-separated-values
Size 258 data points
Discipline Earth System Research
Spatial Coverage (-99.749W, 40.681S, -67.420E, 48.096N); United States of America
Temporal Coverage Begin 2022-05-25T14:45:00Z
Temporal Coverage End 2023-05-12T10:00:00Z