QENS studies of the ammines of magnesium chloride

DOI

The ammoniates of simple salts, such as MgX2 (X=Cl, Br, I), known as ammines, have attracted much interest recently as they offer potential as both hydrogen and ammonia storage materials, amongst other applications. The magnesium halide ammines can accommodate up to 6 equivalents of ammonia (ca. 50 wt%) as [Mg(NH3)n]Cl2 (0 ≤ n ≤ 6) However, there is, as yet, no understanding of the mechanism of ammonia binding and transport through the solid and only qualitative understanding of how and why ammonia binds to the metal centers. Quasi-elastic neutron scattering (QENS) is frequently used to study diffusion of species in solids and allows experimental diffusion coefficients to be extracted via modelling the transport mechanisms. Here we wish to use the OSIRIS QENS to investigate the mobility of ammonia in MgCl2 ammines.

Identifier
DOI https://doi.org/10.5286/ISIS.E.90588121
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/90588121
Provenance
Creator Mrs Jawza Alnawmasi; Dr Franz Demmel; Professor Duncan Gregory; Professor Adrian Porch; Dr Michael Barter; Dr Martin Jones
Publisher ISIS Neutron and Muon Source
Publication Year 2021
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2018-02-19T09:30:00Z
Temporal Coverage End 2018-02-23T08:33:18Z