Lattice dynamics study of filled-skutterudite compounds: RPt4Ge12 (R=Ba, La and Ce)

DOI

The appearance of non-dispersive Einstein (¿rattling¿) modes, known as the phonon-glass paradigm in filled-skutterudite compounds, has been postulated as an origin of the high value of the figure of merit as well as the high heat capacity. However, very recent inelastic neutron scattering measurements by some of us [M. Koza et al Nature Materials 2008] on RFe4Sb12 (R=Ce and La) reveal the absence of rattling modes. Thus it would be very interesting to carry out a systematic study of the phonon modes in filled-skutterudites with different filling of magnetic R-atoms as well as with different transition and metalloid atoms to fully understand the nature of the phonon modes in these materials. We therefore propose to investigate the lattice dynamics of RPt4Ge12, (R=Ba, La, Ce) using the MARI spectrometer.

Identifier
DOI https://doi.org/10.5286/ISIS.E.24077384
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24077384
Provenance
Creator Dr Devashi Adroja; Dr Michael Koza
Publisher ISIS Neutron and Muon Source
Publication Year 2012
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2009-09-26T11:02:43Z
Temporal Coverage End 2009-10-05T10:59:15Z