Light-induced halide ion segregation in hybride perovskites

DOI

We will use X-ray photon correlation spectroscopy to reveal the reversible dynamics of the light-soaking domains in hybrid organic-inorganic perovskites. These domains appear due to light-induced segregation of iodide and bromide ions in MAPb(I/Br)3 films and are characterized by different band gaps and slightly different crystal structures. Using the scattering of coherent X-rays in Bragg geometry, we will characterize the size of the iodine-rich and bromide-rich domains and obtain a characteristic time scale of their formation. This information will help to improve the stability of the perovskite-based solar cells. These kind of experiment can be applicable rather generally to study the ion migration in various soft- and hard-condensed matter systems.

Identifier
DOI https://doi.org/10.15151/ESRF-ES-947339778
Metadata Access https://icatplus.esrf.fr/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatplus.esrf.fr:inv/947339778
Provenance
Creator Federico ZONTONE; Ingrid DAX; Elena CHULANOVA; Rustam RYSOV ORCID logo; Anton PYLYPENKO; Ivan ZALUZHNYY ORCID logo
Publisher ESRF (European Synchrotron Radiation Facility)
Publication Year 2025
Rights CC-BY-4.0; https://creativecommons.org/licenses/by/4.0
OpenAccess true
Representation
Resource Type Data from large facility measurement; Collection
Discipline Particles, Nuclei and Fields