Structures and magnetism of chemical and electrochemical deintercalates of layered manganese oxysulfides

DOI

We propose to use OSIRIS to investigate the changes in magnetic ordering which occur when a series of layered oxysulfides with mixed-valent Mn ions in their oxide layers are oxidised by the deintercalation of Cu from their sulfide layers. These systems complement the mixed-valent Mn oxides and also show a range of magnetic structures which we expect to be able to modify by oxidation. Complex magnetic structures are anticipated which require the long d-spacing capability of OSIRIS. This accompanies an experiment on POLARIS which will correlate the structural chemistry of these systems with composition.

Identifier
DOI https://doi.org/10.5286/ISIS.E.24086018
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24086018
Provenance
Creator Dr Simon Clarke; Dr Alex Corkett; Dr Michael Pitcher; Mr Ray Burns
Publisher ISIS Neutron and Muon Source
Publication Year 2014
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2011-05-31T07:10:19Z
Temporal Coverage End 2011-06-03T08:31:03Z