Non-ionic surfactant induced desorption of a strongly bound cationic layer from mica

DOI

In this proposal we request beamtime to study the unexpected behaviour of a strongly bound bilayer of the cationic surfactant didodecyldimethylammonium bromide on the anionic mica surface in the presence of the non-ionic surfactant hexaethylene glycol monododecyl ether. This builds on previous work at ISIS where a cationic surfactant layer was found to be persistent to an extended wash with water and salt solutions, but upon exposure to sodium dodecyl sulfate at concentrations below the critical micelle concentration the layer thickened, and when the anionic surfactant concentration reached the critical micelle concentration the cationic layer desorped completely from the mica surface.

Identifier
DOI https://doi.org/10.5286/ISIS.E.99688055
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/99688055
Provenance
Creator Miss Holly Smith; Miss Jemima Gasson; Dr Chris Truscott; Professor Stuart Clarke; Mr Fin Allen; Dr Rebecca Welbourn
Publisher ISIS Neutron and Muon Source
Publication Year 2021
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2018-12-06T08:00:00Z
Temporal Coverage End 2018-12-10T08:48:23Z