Crystal and magnetic structures of EuWO1+xN2-x

DOI

Eu2+ d0- transition metal perovskites are of interest as potential multiferroics when undoped, or as CMR materials. EuWO1+xN2-x is a new magnetoresistive material and exists over a broad range of x = -0.2 to 0.5. It has a ferromagnetic ordering transition at TC = 12 K. Neutron diffraction is needed to determine the I112/m monoclinic superstructure evidenced by TEM that arises from O/N ordering and octahedral tilting, and the magnetic order. This may include a coexistence of antiferromagnetic/ ferromagnetic orders (as found in a previous GEM study of the analogueEuNbO2N). 2 days on GEM are needed to study 2 samples with different x values (one stoichiometric x =0, the other highly doped x = 0.5) because of high absorption by Eu.

Identifier
DOI https://doi.org/10.5286/ISIS.E.24071239
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24071239
Provenance
Creator Professor Paul Attfield; Dr Jenny Rodgers; Dr Anna Kusmartseva
Publisher ISIS Neutron and Muon Source
Publication Year 2012
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2009-08-04T13:38:23Z
Temporal Coverage End 2009-08-09T22:22:10Z