Inelastic Neutron Scattering Studies of Gas-Loaded Porous Framework Materials

DOI

This proposed study will investigate the interactions exhibited by some weakly scattering gas substrates (NOx and small hydrocarbons) at different loadings. We request 13 days on TOSCA to study the interaction of adsorbed gas molecules (NO2, NO, N2O, C2H2, C2H4, C2H6, C3H6 and C3H8) within two new porous MOF materials [NOTT-300(V) and NOTT-300(V,Al)]. These MOFs exhibit extremely high selectivity for unsaturated hydrocarbons and NOx at ambient conditions, with high uptake capacities, suggesting the presence of specific guest/host interaction. The proposed study aims to reveal the nature of these selective gas uptake properties by analysing the guest/host interaction.

Identifier
DOI https://doi.org/10.5286/ISIS.E.58449882
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/58449882
Provenance
Creator Dr Zhenzhong Lu; Mr Harry Godfrey; Dr Svemir Rudic; Miss Simona Pili; Mr Jack Humby; Dr Anibal Ramirez-Cuesta; Dr Sam Callear; Professor Bill David; Professor Sihai Yang; Professor Martin Schroder
Publisher ISIS Neutron and Muon Source
Publication Year 2018
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2015-04-09T08:00:00Z
Temporal Coverage End 2015-04-22T08:00:00Z