Temperature Dependence of the Oxidation of Monolayers Under Atmospheric Conditions

DOI

The Earth¿s climate is strongly influenced by clouds. The oxidative processing of pollutants in clouds affects cloud droplet size and optical properties, important climatic effects. Common cloud pollutants are naturally occurring organic surfactants forming organic films on the droplet. The magnitude of climatic effects depends upon the fate of the organic films following atmospheric oxidation. In this work we will measure the oxidation rate of OH radical with stearic acid as a function of temperature. Specifically:-(a) Measure the temperature dependence of the film oxidation rate for typical atmospheric conditions.(b) Determine the activation energy and pre-exponential factors and determine the sources of the activation barrier and describe the transition state.(c) Support an STFC/NERC case award student who will be based at ISIS 2008-2009.

Identifier
DOI https://doi.org/10.5286/ISIS.E.24078889
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24078889
Provenance
Creator Professor Martin King; Dr Christian Pfrang; Professor Adrian Rennie; Miss Claire Lucas; Dr Arwel Hughes; Dr Katherine Thompson
Publisher ISIS Neutron and Muon Source
Publication Year 2012
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2009-12-03T04:17:57Z
Temporal Coverage End 2009-12-05T17:21:17Z