Concentrations and loadings of alkanes in surface sediments of Helgoland Mud Area in the North Sea

DOI

Surface sediment were extracted 4 times by ultrasonication with dichloromethane: methanol (9:1, v/v) for 15 min for FAs and alkanes. For quantification of FAs and alkanes, known amounts of 19-methylarachidic acid and squalane were added as internal standards prior to extraction. Supernatants from each extraction were obtained by centrifugation and combined. The total lipid extracts were concentrated and evaporated under a nitrogen stream. The total lipid extracts were saponified for 2 h at 80 °C with 1 mL of KOH (0.1 M) in methanol: H2O (9:1, v/v). After saponification, the neutral fractions were liquid-liquid extracted with n-hexane and alkanes were eluted from the neutral fractions by silica gel column chromatography with n-hexane. The remaining KOH solution was acidified to pH 1, from which FA were liquid-liquid extracted into dichloromethane. The extracted and dried FAs were converted to methyl ester derivatives (FAMEs) in methanol: HCl (95:5, v/v) at 60 °C for 12 h. After methylation, the FAME fraction was further purified by silica gel column chromatography using dichloromethane: hexane (2:1, v/v) to remove residual polar compounds. FAMEs and alkanes were analyzed on a 7890A gas chromatograph (GC) equipped with a DB-5MS fused silica capillary column (60 m, 250 µm, 0.25 µm) and a flame ionization detector (FID). Peak areas were determined by integrating the respective peaks and concentrations were calculated against the internal standards. FAME contents were subsequently corrected for the derivative methyl carbon to determine FA contents. FAs and alkanes were normalized to OC content.

Identifier
DOI https://doi.pangaea.de/10.1594/PANGAEA.971522
Related Identifier IsPartOf https://doi.pangaea.de/10.1594/PANGAEA.971520
Metadata Access https://ws.pangaea.de/oai/provider?verb=GetRecord&metadataPrefix=datacite4&identifier=oai:pangaea.de:doi:10.1594/PANGAEA.971522
Provenance
Creator Wei, Bingbing ORCID logo; Holtappels, Moritz ORCID logo
Publisher PANGAEA
Publication Year 2024
Funding Reference Federal Ministry of Education and Research https://doi.org/10.13039/501100002347 Crossref Funder ID 03F0874D https://foerderportal.bund.de/foekat/jsp/SucheAction.do?actionMode=view&fkz=03F0874D Ozeane unter Stress: APOC - Anthropogene Einflüsse auf den Kreislauf partikulären organischen Kohlenstoffs in der Nordsee; German Research Foundation https://doi.org/10.13039/501100001659 Crossref Funder ID 390741603 https://gepris.dfg.de/gepris/projekt/390741603 EXC 2077: The Ocean Floor – Earth's Uncharted Interface
Rights Creative Commons Attribution 4.0 International; Data access is restricted (moratorium, sensitive data, license constraints); https://creativecommons.org/licenses/by/4.0/
OpenAccess false
Representation
Resource Type Dataset
Format text/tab-separated-values
Size 992 data points
Discipline Earth System Research
Spatial Coverage (7.920W, 53.898S, 8.707E, 54.230N); North Sea
Temporal Coverage Begin 2022-03-17T13:11:45Z
Temporal Coverage End 2022-03-30T16:07:52Z