Hydrogen diffusion in zirconium alloys: The role of beta-phase morphology, cold work and the anisotropy of the hcp crystal sturcture

DOI

Zr is used extensively in nuclear reactors worldwide in a broad range of microstructural conditions due to its thermomechanical, corrosion and neutronic properties. However the affinity between H and Zr leaves Zr-alloys susceptible to ZrH precipitation and delayed hydride cracking (DHC); a process controlled by the diffusion of H. The purpose of this work is to characterize the effect of the beta-Zr phase, cold work, grain morphology and anisotropy of the Zr hcp lattice on H mobility; building on the platform established by J.R. Santisteban et. al., whom have used neutronic techniques for the non-destructive determination of low H content in metals. On successful completion of this work in-situ experiments will be carried out on hydrogenated samples subjected to stress and the H diffusion to a stress concentration monitored providing fundamental insight into the DHC process.

Identifier
DOI https://doi.org/10.5286/ISIS.E.24088550
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24088550
Provenance
Creator Dr Javier Santisteban; Professor Mark Daymond; Dr Anton Tremsin; Dr Laura Barrow; Dr Andrew Barrow; Professor Michael Fitzpatrick; Mr Robin Woracek
Publisher ISIS Neutron and Muon Source
Publication Year 2015
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2012-03-24T12:49:15Z
Temporal Coverage End 2012-10-16T10:38:43Z