The crystal structure of multiferroic CuO

DOI

Despite its simple chemical formula, cupric oxide (CuO) has a surprisingly complex magnetic behaviour which remains only partly understood. Interest in CuO has recently resurfaced with the discovery of a magnetically-induced multiferroic phase at high temperatures. Neutron scattering has revealed that the multiferroicity is accompanied by a change in the magnetic structure from a commensurate antiferromagnet at low T, to an incommensurate helical structure in the multiferroic phase. We have investigated the spin dynamics and magnetoelectric behaviour in CuO, to understand the mechanism that drives the multiferroic phase. We have recently measured the complete spin-wave spectrum throughout the Brillouin zone, but we have found that the data cannot be modelled within the symmetry imposed by the published crystal structure. We therefore wish to use HRPD to determine the structure of CuO.

Identifier
DOI https://doi.org/10.5286/ISIS.E.89608938
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/89608938
Provenance
Creator Dr Henrik Jacobsen; Professor Andrew Boothroyd; Dr Alexandra Gibbs
Publisher ISIS Neutron and Muon Source
Publication Year 2020
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Natural Sciences; Physics
Temporal Coverage Begin 2017-11-27T08:00:00Z
Temporal Coverage End 2017-11-29T08:43:40Z