Local and average structures of the proton conducting Y-doped BaZrO3 from neutron diffraction and pair distribution function analysis

DOI

Y-doped BaZrO3 has been identified as a promising potential candidate as an electrolyte materialfor proton conduction in intermediate temperature fuel cells. In the temperature range of 200-400°C it has similar conductivities as oxygen conduction materials at 700°C and shows greaterstability in a range of atmospheres compared to other proton conducting candidates. Reducingoperating temperatures will lead to viable commercialisation of these devices due to the decrease in fabrication costs and extended lifetime. This proposal seeks to study the effect of Y-doping and water doping (D2O) on the local structure of Y-doped BaZrO3 by PDF analysis derived from total neutron scattering experiments. This will result in greater understanding of the structural modifications which occur on the short range order and correlate them to the conductivity properties.

Identifier
DOI https://doi.org/10.5286/ISIS.E.24089659
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24089659
Provenance
Creator Dr Matthew Dunstan; Mr Luke Sperrin; Professor Clare Grey
Publisher ISIS Neutron and Muon Source
Publication Year 2015
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2012-10-30T15:30:45Z
Temporal Coverage End 2012-11-02T07:20:02Z