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INS study of the effect of particle size on the formation of beta-palladium h...
Finely divided, supported palladium particles are used as catalysts in many technical processes. However, there is still considerable potential to improve catalyst performance... -
Insulator to metal transition in TiOCl at high pressures
We propose to study the high temperature structure of TiOCl where a pressure induced metal to insulator transition has been reported recently by Kuntscher et al.Due to our... -
Equations of state of D2O ice III and ice V
The high-pressure forms of ice, phases III and V, are the equilibrium solids in contact with liquid water at pressures between 2.5 - 5.5 kbar. Consequently, their properties are... -
Thermoelastic properties of ammonium sulfate, (ND4)2SO4, and the P-T dependen...
Ammonium sulfate exhibits a first-order phase transition upon cooling through ~ 224 K at room pressure, from a paraelectric to a ferroelectric crystal. There have been no... -
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The icy-moon analogue of MgSiO3-perovskite: MgSO4.9H2O a high-pressure study
Mg-sulfate 11-hydrate (meridianiite) is decomposed by pressure to form Mg-sulfate 9-hydrate + ice, a process that will occur in the mantles of large icy planetary bodies and... -
Pressure driven phase transitions in antiferroelectric, PbZrO3
Antiferroelectric materials are attracting extensive attention due to their potential in energy storage applications. These materials exhibit a double polarisation-field... -
The quest for fully hydrogen-ordered ice XIV
Water ice displays a remarkably complex phase diagram containing pairs of hydrogen-ordered / disordered phases. Ice XII is a hydrogen-disordered phase and ice XIV is its... -
Local ordering in the pressure-induced order-disorder transition in ammonium ...
Ammonium bromide undergoes a pressure-induced order-disorder transition, where the disordered (plastic) phase is thought to consist of a random distribution of ammonium cations... -
Phase transitions in melamine at high pressure
Melamine is a common organic molecule based on a six-sided ring; this unit typically connects with itself or other organic species to form layered crystal structures, which then... -
Onset of classical dynamics in ammonium hexachlorometallates.
The piloting experiment (RB 820239) on VESUVIO on (NH4)2PdCl6, has shown that, at 5 and 80K, H momentum distribution, J(y), in NH4+ is non-Gaussian with non-vanishing... -
Nuclear quantum dynamics across the structural phase transition in an organic...
Inspired by the calorimetric and dielectric properties studies on a novel organic anitferroelectric compound, dtBBP - CLA , this proposal seeks to compare and extend the... -
Phase diagram of a switchable dielectric framework near the critical point
The family of hybrid Prussian blue analogues includes many electroactive materials, where organic cations moving within the pores of the cyanide framework cause unusual and... -
UNDER PRESSURE: an alternative route to novel zeolite catalysts
Zeolites are microporous aluminosilicate minerals which are characterised by their highly crystalline framework structures. Having distinct porosity, zeolites are used in a... -
Compressibility and Tilting of Polyhedra within Sr2NiMoO6 at High Pressure
Ordered double perovskites (also known as elpasolites) have the general formula A2BBO6 where A is generally a rare earth metal or alkaline earth metal and where B and B are...