In situ investigation of the lattice dynamic of the DUT-8(M) MOFs M2(2,6­ndc)2dabco (M - Co, Zn, Cu) by inelastic neutron scattering

PID

Switchable MOFs are unique materials, which are able to transform their crystal structure from a dense or less porous to a highly porous state and vice versa as response to the external stimuli. In order to get a deeper insights into switching mechanism, low-frequency vibrations, responsible for the lattice dynamic, typically appearing below 100 cm-1 (terahertz region) should be studied in details. Inelastic neutron scattering shows a plenty of advantages over optic spectroscopy methods, because of the different rules governing intensity of the vibrational features and therefore is highly suitable for detail investigation of the switching mechanism in flexible MOFs. Herein we apply for the beamtime for temperature-dependent and control gas atmosphere INS measurements on DUT-8(M) (M – Co, Zn and Cu), which will complement the data, collected earlier on DUT-8(Ni) system.

Identifier
PID https://hdl.handle.net/21.11151/q0xx-bdxa
Related Identifier IsCompiledBy https://doi.org/10.5442/NI000002
Related Identifier IsCompiledBy https://doi.org/10.5442/NI000012
Metadata Access https://data.helmholtz-berlin.de/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:data.helmholtz-berlin.de:inv/7515
Provenance
Instrument E9 - Fine Resolution Powder Diffractometer (FIREPOD), ; V3 - Time-of-Flight Spectrometer (NEAT),
Publisher Helmholtz-Zentrum Berlin für Materialien und Energie
Contributor Bon, Volodymyr; Senkovska, Irena; Kaskel, Stefan; Helmholtz-Zentrum Berlin für Materialien und Energie
Publication Year 2024
Rights Creative Commons Zero v1.0 Universal; https://creativecommons.org/publicdomain/zero/1.0/
OpenAccess true
Representation
Resource Type Investigation; Collection
Size 1.79 GiB
Discipline Other
Temporal Coverage Begin 2019-02-04T08:00:00Z
Temporal Coverage End 2019-04-16T07:02:16Z