Copy of: IINS Study of the Molecular Properties of Hydrogen Peroxide/Water Mixtures of Different Concentration

DOI

Hydrogen Peroxide is one of the cleanest, most versatile strategic base chemicals available. It is used at the large scale as oxidising agent in the chemical industry, as a propellant in rocket and satellite technology, mining industry, precious metal recycling, desinfectant and many other applications. Often the use of high concentrated H2O2 is essential. However, due to the limited accessability and handling capability the physical/chemical properties at concentrations of aqueous preparations up to 87% or 98% H2O2 content are still unresolved. Especially differences in the degree of molecular association, O-O bond lengths and hydrogen bonding deserve attention. We propose to compare the IINS spectra of a set of hydrogen peroxide preparations of increasing concentration using TOSCA (translational, librational and HO-OH torsions) and MAPS (H-O-H bend, H-OOH bend and O-H stretch).

Identifier
DOI https://doi.org/10.5286/ISIS.E.24089903
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24089903
Provenance
Creator Professor Stewart Parker; Dr Peter Albers; Dr Juergen Glenneberg
Publisher ISIS Neutron and Muon Source
Publication Year 2016
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2012-11-27T08:56:35Z
Temporal Coverage End 2013-03-19T07:42:55Z