Diamond Experiment MT20586 "Incommensurate modulation in a multiferroic metal formate perovskite",

DOI

The metal formate perovskites have structural chemistry as diverse as their inorganic analogues; yet substantial areas of their phase diagrams, including phases with potentially useful functionality, remain unexplored. Using I19 data, we recently observed a low-temperature incommensurately modulated phase in methylammonium manganese formate and solved its structure. This will be the first modulated structure reported in this family and offers a potential novel route to achieving electrical order. Here we seek to measure how the modulation varies with temperature, including any lock-in to a commensurate structure; and to understand the differences between this material and the cobalt analogue, which has quite different low-temperature phase behaviour. Combining single-crystal X-ray and high resolution powder neutron data is a very powerful way to shed light on subtle structural changes.

Identifier
DOI https://doi.org/10.5286/ISIS.E.98019990
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/98019990
Provenance
Creator Dr Richard Dixey; Mr Zhengqiang Yang; Dr Anthony Phillips; Dr Dominic Fortes
Publisher ISIS Neutron and Muon Source
Publication Year 2021
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2018-09-27T09:00:00Z
Temporal Coverage End 2018-09-30T07:38:10Z