Penetration and reaction of hydroxyl radical into organic films at the air-water interface

DOI

The Earth¿s climate is strongly influenced by clouds. The oxidative processing of pollutants in clouds affects droplet size and optical properties, important climatic effects. Common cloud pollutants are naturally occurring organic surfactants forming organic films on the droplet. The climatic effect depends on the rate of atmospheric oxidation of these films and whether any product film forms. In this work we will study the kinetics of hydroxyl radical with palmitic acid. Specifically we will (a) demonstrate that a common aqueous cloud oxidant, OH radical, can penetrate deep into the organic film and remove the film, (b) calculate the effect of the reaction on the hygroscopic properties of a cloud droplet and demonstrate removal of the organic film may cause a cloud to evaporate, (c) Support a STFC/NERC CASE award PhD student¿s final year studies.

Identifier
DOI https://doi.org/10.5286/ISIS.E.24079727
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24079727
Provenance
Creator Dr Arwel Hughes; Dr Katherine Thompson; Professor Adrian Rennie; Professor Martin King; Miss Claire Lucas
Publisher ISIS Neutron and Muon Source
Publication Year 2013
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2010-05-19T08:00:20Z
Temporal Coverage End 2010-05-22T12:04:15Z