QENS studies of hydride ion diffusion in alkaline earth hydrides

DOI

We propose to study hydride ion diffusion in AEH2 (AE = Ca and Ba) using the QENS technique. We have recently demonstrated that the charge carrier in these materials are hydride ions (H-). A previous neutron study employing the new high temperature and conductivity sample environment jointly developed by ISIS and the University of St Andrews for use in ISIS diffractometers further strengthened the case (RB1410181), and QENS will supplement these studies with quantitive data on diffusion mechanistic steps. QENS has been used extensively to study the diffusion of ions in solids. More specifically, proton and hydride ion diffusion have been studied to elucidate diffusion (and conductivity) mechanistic steps such as average ionic jump distances and frequency as well as jump positions.

Identifier
DOI https://doi.org/10.5286/ISIS.E.58450299
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/58450299
Provenance
Creator Dr Lewis Downie; Professor John Irvine; Dr Martin Jones; Dr Julia Payne; Dr George Carins; Dr Maarten Verbraeken; Mr Amane ABDOUN; Dr Cristian Savaniu; Dr Franz Demmel
Publisher ISIS Neutron and Muon Source
Publication Year 2018
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2015-04-22T08:00:00Z
Temporal Coverage End 2015-04-27T08:00:00Z