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Ionic disorder and phase transition studies of Lightweight Hydrides LiBH4 and...
We ask for 3 days on EMU to study the Muon spectroscopy of both LiBH4 and Ca(BH4)2 as a function of temperature from 90K-650K. These materials have been extensively... -
Inelastic Neutron Spectroscopy Study of Ammonium Borohydride
Ammonium borohydride (ABH2) has been studied as a hydrogen storage material, it stores hydrogen on both cationic and anionic sites and has the largest gravimetric and volumetric... -
Investigation of the core-shell interaction in stabilised PdAu nanoparticle c...
Bimetallic nanoparticles are attractive materials due to their novel electronic, magnetic optical and catalytic properties which are distinctly different from those of their... -
Investigation of molecular rotation and disorder in methylamine borane (CH3NH...
We request 3 days on TOSCA to study molecular rotations of NH4+ and BH4- ions and the ionic disorder in ammonium borohydride (rock salt lattice) and its methylated derivative.... -
In-situ neutron diffraction studies of hydrogen desorption and reversibility ...
We ask for 4 days beam time on GEM to study the dehydrogenation and subsequent rehydrogenation of Mg(11BD4)2. Mg(BH4)2 is currently one of the most promising lightweight... -
A unique borohydride bridged dimer of Ni(I)
The reaction of Ni(6-Mes)(PPh3)Br (6-Mes = bis(1,3-(2,4,6-trimethylphenyl)imidazol-2-ylidene) with 2.5 equivalents of NaBH4 leads to formation of product characterised as... -
In-situ Specific Heat Measurements and Order Disorder Phase Transition Studie...
We request 4 days on HRPD to perform combined specific heat and neutron powder diffraction measurements of C60 and the molecular hydrogen storage materials, ammonia borane and... -
Ionic disorder studies of lightweight hydrides by VESUVIO
We ask for 8 days on VESUVIO to study the momentum distribution of LiBH4, Li2NH and Li1+xNH2-x as a function of temperature from 10K-653K (depending on sample). Li2NH and... -
Study of NH4+ mobility in ammonia borane, ammonium borohydride and methyl amm...
We request 5 days on EMU to study the NH4+ ion mobility in the light borohydride materials NH3BH3, NH4BH4 and CH3NH3BH4. As has been proposed by Stowe et al., during the...