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Structural investigation of the high temperature phases in ammonium iodate
We will investigate the structures of the high temperature (RT to 400K) phases of ammonium iodate, and the features that accompany these phase transitions. From our previous... -
In-situ reaction of lithium amide or imide with manganese(IV) oxide
We request 3 days beam time on POLARIS for in-situ powder diffraction studies of the reactions of lithium amide or lithium imide with manganese(IV) oxide under flowing argon or... -
Towards the development of lithium manganese nitride as novel two stage regen...
In the last decades the production and consumption of reactive nitrogen increased exponentially due to the extensive utilisation of nitrogen containing compounds as fertilizers... -
Molecular Dynamics in Polymer Nanocomposites
Our aim is to determine whether the fast dynamics, of either the backbone or the phenyl ring of polystyrene, are altered by the presence of carbon nanotubes, and, if so, whether... -
A new plastic phase in PCBM from low-energy inlelastic neutron scattering
Phenyl-C61-butyric acid methyl ester (PCBM) is a fullerene-based material of high technological interest due to its use in organic solar photovoltaic cells. A better... -
Hydrogen from ammonia using lithium imide metal nitride composites
Light metal amides and imides are a new class of highly active ammonia decomposition catalysts. Indeed, composites of lithium imide and transition metal nitrides are likely to... -
Molecular motions in novel water-soluble organometallic gels
The aim of this proposal is to study the internal dynamics of a novel organometallic polymers based on two metal-containing moieties -Ru, Au- bridged through a tridentate... -
In-situ neutron powder diffraction studies of non-stoichiometry in Na battery...
We request 3 days on POLARIS to study the detailed crystal structure of a sodium battery cathode material that is currently under consideration for use in commercial sodium... -
Monomer dynamics in polymer nanocomposites
We have recently shown that the addition of single walled carbon nanotubes produces a minimum in the diffusion coefficient with increasing nanoparticle concentration. Initially,... -
Monomer dynamics in polymer nanocomposites
We have recently shown that the addition of single walled carbon nanotubes produces a minimum in the diffusion coefficient with increasing nanoparticle concentration. Initially,... -
Ammonia synthesis using lithium hydride-metal nitride composites: an in situ ...
The development of more active catalysts for the production of ammonia will have a worldwide impact on the energy cost of producing fertiliser. Composites of lithium hydride and... -
In-situ studies of amides with ammonia
The aim of this proposal is to determine that materials that are present in the ammoniation of amides. -
Molecular weight dependence of 2D-confined dynamics in glass-forming systems
We seek to explore the dynamics of glass forming systems upon extreme 2D-confinement. These experiments are motivated by preliminary experiments on oligomers and macromolecules... -
Electrostatic interaction effects in orientationally disordered phases
Plastic phases are characterized by a positional ordering of the molecular centers of mass while molecules are rotating in a hindered way. Therefore these phases are... -
Neutron Diffraction study on two novel topological Dirac semimetal candidates...
Dirac fermions with linear energy dispersion with momentum space have been of current interest for spintronic applications because a variety of quantum transport phenomena... -
Hydrogen production from ammonia using lithium imide: an isotope study
We have recently discovered that light metal amides and imides are excellent cattalysts for the decomposition of ammonia. We request 3 days on POLARIS to perform in situ neutron... -
The structure of aprotic and aromatic solvents
In this proposal we would like to study the structure of polar aprotic and aromatic liquids using H/D and 15N/*N isotopic labelling on SANDALS. The molecules chosen for study... -
Dynamics and phase behaviour of Fullerol using low energy neutron spectroscopy
Fullerene and its derivatives have become materials of great technological interest for a number of reasons including their success as electron acceptors in organic photovoltaic... -
Studying the dynamics of PVA/graphene nanocomposites
The unique properties of graphene make it one of the best candidates as reinforcement of polymeric nanocomposites. One such case are poly(vinyl alcohol) (PVA)/graphene... -
Understanding the decomposition of ammonia by lithium-calcium imide
Among light metal amide-imide catalysts for ammonia decomposition, lithium-calcium imide is the most promising candidate for practical application. Ex situ diffraction data...