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Local structure in PMN-PT relaxor ferroelectrics
The proposed experiments will provide neutron total-scattering data for elucidating the nanoscale ordering of polar atomic displacements that underlie the commercially viable... -
Total scattering measurements for local structure determination in novel redu...
Nuclear fusion offers safe and sustainable power generation, without the production of long-lived radioactive wastes. Fusion core structural materials will be subjected to... -
New brownmillerite-based oxide ion conductors: Local structure and structure-...
Oxide ion conductors are key components in a number of technologically important applications. Our research programme on the development of new oxide ion conductors, using... -
Nanoscale Segregation and Order-Disorder in Ceria-Zirconia Catalysts
This proposal is concerned with understanding the properties of materials used in important applications in catalysis and energy, such as in molecular transformations of exhaust... -
Insights into the structure of mechanochemically-synthesised ternary lithium ...
In the current work, we study inorganic solid-state electrolytes for lithium-ion batteries. These materials, unlike the traditional liquid electrolytes, could lead to a... -
Local structure in lanthanum oxyfluorides - probing ion transport in fuel cel...
Mixed-anion compounds such as lanthanum oxyfluorides are increasingly attractive as materials in energy technology applications, such as fuel cells, electrolysers and permeation... -
Local structure studies by PDF analysis of novel Li-rich double perovskites a...
Recently, our group has prepared a series of new double perovskite materials (Li1.5La1.5MO6, M=W6+, Te6+) which display interesting electrochemical behaviour for use in Li-ion... -
Understanding transition metal, oxygen and proton local order in proton condu...
Proton conducting materials have received widespread attention in recent years, due to their rich potential in the areas of energy related research, sensors and membranes. Here,... -
Local structure of the ferroelectric and giant barocaloric (ND4)2SO4
Ammonium sulfate has a well-known order-disorder phase transition at -50 ºC: initially of interest for the ferroelectric behaviour in the low-temperature phase, this has... -
Probing Transition Metal Migration in Cathode Materials for Na-ion Batteries ...
Sodium layered oxides as cathode for Na-ion battery could exceed the energy density offered by Li-ion cathode thanks to two main advantages: (i) the activation of Fe3+/Fe4+ in... -
Atomic-Scale Structure of Mixed-Metal Carbo-nitrides From Total Neutron Scatt...
Our aim is to use total neutron scattering to determine pair distribution functions that will allow us to examine the atomic-scale structure of some new mixed-metal... -
Probing the Evolution of Local Structure in Disordered Li-rich Cathode Materi...
The next generation of Li-ion rechargeable batteries is contingent on the development of new positive electrode materials with a greater capacity to store charge. Highly ordered... -
Configurational and displacive disorder in the cubic NTE material Cd(CN)2
Cubic cadmium(II) cyanide shows the most pronounced isotropic NTE effect known, with behaviour more than twice as extreme as that of better known materials such as ZrW2O8. This... -
PDF study of the structural disorder in a quantum spin liquid candidate
We have identified a potential quantum spin liquid by tuning the magnetic interactions on a square lattice through d10-d0 cation mixing. MuSR shows dynamic magnetism down to... -
Investigation into the Effect of Heating Rates on Recrystallisation Mechanism...
Electrical steels (ES) used in motors and transformers. The major challenge is to optimise themagnetic property of ES to reduce energy waste during service. The crystallographic... -
A total scattering study of the phase transitions in the hybrid organic-inorg...
Hybrid organic-inorganic perovskites are interesting candidates for a range of applications, from solar cells to light emitting diodes and lasers. For the latter applications... -
Reversible Redox in a Cerium (IV) Germanate Scheelite: a New Oxygen Storage M...
Materials that show oxide-ion mobility (solid electrolytes) and/or reversible uptake and release of oxygen (oxygen storage materials) have important uses in applications... -
Conduction Pathways in Alkali Lanthanide Pyrosilicates, A3LnSi2O7
Alkali Lanthanide Pyrosilicates (general formula = A3LnSi2O7) are promising candidates for use as solid electrolytes in all solid state Li-ion and Na-ion batteries. To date the... -
Unpicking the signal of partial order from thermal motion in diffuse scatteri...
Orientationally-disordered water molecules in ice adopt a degree of partial order upon cooling, a process that is halted by kinetics at ~100 K in pure ice and ~60 K in KOH-doped... -
Total scattering of Zintl phase deuterides CaSiD1.3, BaSiD1.9 and SrGeD1.3
The Zintl phase hydrides CaSiH1.3, BaSiH1.9 and SrGeH1.3 exhibit hydride anions in alkaline earth metal voids as well as hydrogen bound to the polyanions formed by silicon /...