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Investigating the diffusion of E-caprolactam in hierarchically-porous catalys...
Caprolactam (CL) is a high-value chemical and precursor to nylon-6. Industrially, a harsh, liquid-acid catalyst effects the Beckmann rearrangement of C6-oxime to CL, but the... -
Cation reorientation dynamics in a hybrid Prussian blue analogue
The cubic pores in many Prussian blue analogues are big enough to contain organic cations. In the material (HIm)2K[Fe(CN)6], the imidazolate guest cation is free to rotate in... -
Investigating the diffusion of cyclic oximes in hierarchically-porous catalys...
Caprolactam (CL) is a high-value chemical precursor to nylon-6. On an industrial scale an aggressive liquid-acid catalyst is used to transform C6-oxime to CL. Due to...