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Vibrational properties of ammine complexes
Our intention is to study the INS spectra of ammine complexes nNH3LiBH4 (with n = 1,2,3,4) and nNH3LiI (n=1). Ammine complexes (MXm(NH3)n), amides (M(NH2)m), and imides... -
Structural studies of the cycling and decomposition of Mg(NH3)6(BH4)2
Given its high hydrogen gravimetric density, ammonia may be utilised as a hydrogen carrier, and thus ammonia stores are an area of interest. It is known that Mg(BH4)2 takes up... -
Ammonia adsorption studies of Li(11)BD4 and Mg((11)BD4)2
On exposure to ammonia, LiBD4 and Mg(BD4)2 form the respective ammoniates, Li(11)BD4(ND3)n and Mg((11)BD4)2(ND3)6. We have identified the decomposition temperatures, kinetics... -
Structural Studies of Li(ND3)n11BD4
On exposure to ammonia, Li(11)BD4 forms the ammoniate Li(11)BD4(ND3)n. Our recent experiment (RB820252) has shown that there are four distinct crystalline phases in the...
